Казанский (Приволжский) федеральный университет, КФУ
КАЗАНСКИЙ
ФЕДЕРАЛЬНЫЙ УНИВЕРСИТЕТ
 
THERMODYNAMIC PROPERTIES OF PHASE TRANSITION OF 2-METHYLQUINOLINE, 2-CHLOROQUINOLINE AND 2-PHENYLQUINOLINE
Форма представленияТезисы и материалы конференций в российских журналах и сборниках
Год публикации2022
  • Соломонов Борис Николаевич, автор
  • Другие авторы Абдулла Раванд Самад Абдулла
  • Абдулла Раванд Самад Абдулла, автор
  • Библиографическое описание на языке оригинала THERMODYNAMIC PROPERTIES OF PHASE TRANSITION OF 2-METHYLQUINOLINE, 2-CHLOROQUINOLINE AND 2-PHENYLQUINOLINE
    Аннотация Quinoline derivatives are extremely useful in medicine. Therefore, thermodynamic properties of them are essential to know their quality and stability. The medicine may expose to phase transition during setting under struggle environments or transportation conditions. Consequently, thermodynamic characters of phase transition for 2-methylquinoline (Quinaldine), 2-chloroquinoline and 2-phenylquinoline were investigated. The sublimation/vaporization enthalpy of the compounds were determined by using solution calorimetry-additivity scheme approach. Solution calorimetry was used to measure solution enthalpies of the compounds in benzene solvent at 298.15 K. Solvation enthalpy of the compounds were calculated by additivity scheme method. In addition, transpiration method was applied to determine vapor pressures over 2-Chloroquinoline for first time. Sublimation/vaporization enthalpy, entropy, and free energy for 2-methylquinoline, 2-chloroquinoline and 2-phenylquinoline were determined from
    Ключевые слова evaporation enthalpy, solvation enthalpy, solution calorimetry, additive scheme and thermochemical properties.
    Место издания Казань
    URL https://rcct2021.kpfu.ru/
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