КФУ. Карточка публикации. Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I)

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BOND LENGTHS AND ATOMIC RADII IN COMPOUNDS EX3 (E = N, P, AS, SB; X = F, CL, BR, I)

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2022

Язык

английский

Авторы, сотрудники КФУ

Халитов Карим Фаритович, автор

Библиографическое описание на языке оригинала

Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) / K. F. Khalitov and F. G. Khalitov // Russian Journal of Physical Chemistry A, 2022, Vol. 96, No. 11, pp. 2425–2431

Аннотация

Abstract—Correlations between bond lengths d and the first ionization potentials of atoms and molecules are established on the basis of experimental data. Functional dependences are obtained for the series of compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) when Х or E are substituted. The difference between dependences with varied E or Х are explained by the differing effects on electron pairs of ion E3−. A way of estimating the values of ion radii RE for the elements N, P, As, and Sb is proposed. Interdependences of the values of radii of ions, their dipole moments, and refractions are discussed. The effect substituents X have on the values of radii RE is shown. The values of radii RE(3−) are evaluated for spherically symmetric ions. Linear dependences of radii RE(3−) and ionization potentials of the corresponding ions E3− and atoms of inert gases on their effective charges are established.

Ключевые слова

bond length, ionization potential, compounds EX3 (E = N, P, As, Sb), radii of elements N, P, As, Sb, dipole moments

Название журнала

RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A

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Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Халитов Карим Фаритович	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) / K. F. Khalitov and F. G. Khalitov // Russian Journal of Physical Chemistry A, 2022, Vol. 96, No. 11, pp. 2425–2431	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=272093	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A	ru_RU
dc.description.abstract	Abstract—Correlations between bond lengths d and the first ionization potentials of atoms and molecules are established on the basis of experimental data. Functional dependences are obtained for the series of compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I) when Х or E are substituted. The difference between dependences with varied E or Х are explained by the differing effects on electron pairs of ion E3−. A way of estimating the values of ion radii RE for the elements N, P, As, and Sb is proposed. Interdependences of the values of radii of ions, their dipole moments, and refractions are discussed. The effect substituents X have on the values of radii RE is shown. The values of radii RE(3−) are evaluated for spherically symmetric ions. Linear dependences of radii RE(3−) and ionization potentials of the corresponding ions E3− and atoms of inert gases on their effective charges are established.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	bond length	ru_RU
dc.subject	ionization potential	ru_RU
dc.subject	compounds EX3 (E = N	ru_RU
dc.subject	P	ru_RU
dc.subject	As	ru_RU
dc.subject	Sb)	ru_RU
dc.subject	radii of elements N	ru_RU
dc.subject	P	ru_RU
dc.subject	As	ru_RU
dc.subject	Sb	ru_RU
dc.subject	dipole moments	ru_RU
dc.title	Bond Lengths and Atomic Radii in Compounds EX3 (E = N, P, As, Sb; X = F, Cl, Br, I)	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU