КФУ. Карточка публикации. Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows

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ND3+, YB3+: YF3 OPTICAL TEMPERATURE NANOSENSORS OPERATING IN THE BIOLOGICAL WINDOWS

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2022

Язык

английский

Авторы, сотрудники КФУ

Гафуров Марат Ревгерович, автор

Киямов Айрат Газинурович, автор

Олейникова Екатерина Ильинична, автор

Пудовкин Максим Сергеевич, автор

Черосов Михаил Андреевич, автор

Библиографическое описание на языке оригинала

Pudovkin, M., Oleynikova, E., Kiiamov, A., Cherosov, M., & Gafurov, M. (2022). Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows. Materials, 16(1), 39.

Аннотация

This work is devoted to the study of thermometric performances of Nd3+ (0.1 or 0.5 mol.%), Yb3+ (X%):YF3 nanoparticles. Temperature sensitivity of spectral shape is related to the phonon-assisted nature of energy transfer (PAET) between Nd3+ and Yb3+). However, in the case of single-doped Nd3+ (0.1 or 0.5 mol.%):YF3 nanoparticles, luminescence decay time (LDT) of 4F3/2 level of Nd3+ in Nd3+ (0.5 mol.%):YF3 decreases with the temperature decrease. In turn, luminescence decay time in Nd3+ (0.1 mol.%):YF3 sample remains constant. It was proposed, that at 0.5 mol.% the cross-relaxation (CR) between Nd3+ ions takes place in contradistinction from 0.1 mol.% Nd3+ concentration. The decrease of LDT with temperature is explained by the decrease of distances between Nd3+ with temperature that leads to the increase of cross-relaxation efficiency. It was suggested, that the presence of both CR and PAET processes in the studied system (Nd3+ (0.5 mol.%), Yb3+ (X%):YF3) nanoparticles provides higher temperature sensitivity compared to the systems having one process (Nd3+ (0.1 mol.%), Yb3+ (X%):YF3). The experimental results confirmed this suggestion. The maximum relative temperature sensitivity was 0.9%?K−1 at 80 K.

Ключевые слова

lifetime thermometry; Nd3+, Yb3+:YF3; optical temperature sensors

Название журнала

Materials

URL

https://www.mdpi.com/1996-1944/16/1/39

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https://repository.kpfu.ru/?p_id=274925

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Гафуров Марат Ревгерович	ru_RU
dc.contributor.author	Киямов Айрат Газинурович	ru_RU
dc.contributor.author	Олейникова Екатерина Ильинична	ru_RU
dc.contributor.author	Пудовкин Максим Сергеевич	ru_RU
dc.contributor.author	Черосов Михаил Андреевич	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Pudovkin, M., Oleynikova, E., Kiiamov, A., Cherosov, M., & Gafurov, M. (2022). Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows. Materials, 16(1), 39.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=274925	ru_RU
dc.description.abstract	Materials	ru_RU
dc.description.abstract	This work is devoted to the study of thermometric performances of Nd3+ (0.1 or 0.5 mol.%), Yb3+ (X%):YF3 nanoparticles. Temperature sensitivity of spectral shape is related to the phonon-assisted nature of energy transfer (PAET) between Nd3+ and Yb3+). However, in the case of single-doped Nd3+ (0.1 or 0.5 mol.%):YF3 nanoparticles, luminescence decay time (LDT) of 4F3/2 level of Nd3+ in Nd3+ (0.5 mol.%):YF3 decreases with the temperature decrease. In turn, luminescence decay time in Nd3+ (0.1 mol.%):YF3 sample remains constant. It was proposed, that at 0.5 mol.% the cross-relaxation (CR) between Nd3+ ions takes place in contradistinction from 0.1 mol.% Nd3+ concentration. The decrease of LDT with temperature is explained by the decrease of distances between Nd3+ with temperature that leads to the increase of cross-relaxation efficiency. It was suggested, that the presence of both CR and PAET processes in the studied system (Nd3+ (0.5 mol.%), Yb3+ (X%):YF3) nanoparticles provides higher temperature sensitivity compared to the systems having one process (Nd3+ (0.1 mol.%), Yb3+ (X%):YF3). The experimental results confirmed this suggestion. The maximum relative temperature sensitivity was 0.9%?K−1 at 80 K.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	lifetime thermometry; Nd3+	ru_RU
dc.subject	Yb3+:YF3; optical temperature sensors	ru_RU
dc.title	Nd3+, Yb3+: YF3 Optical Temperature Nanosensors Operating in the Biological Windows	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU