| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2022 |
| Язык | английский |
|
Гришаев Денис Юрьевич, автор
|
|
Андреева Вера Владимировна, автор
Иванова Елизавета Сергеевна, автор
Марьясов Максим Александрович, автор
Насакин Олег Евгеньевич, автор
|
| Библиографическое описание на языке оригинала |
Nasakin O. E. New Multifunctional Synthon in Organic Chemistry / O. E. Nasakin, E. S. Ivanova, M. A. Marya-sov, V. V. Andreeva, O. A. Lodochnikova, D. Yu. Grishaev // SSRN.-2022.-P.17 |
| Аннотация |
SSRN |
| Ключевые слова |
unsymmetrical dimethylhydrazine, methylene dimethylhydrazone, tetracyanoethylene, tetracyanoketones, Thorp-Ziegler type cyclization |
| Название журнала |
SSRN
|
| URL |
https://ssrn.com/abstract=4272817 or http://dx.doi.org/10.2139/ssrn.4272817 |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=295505 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Гришаев Денис Юрьевич |
ru_RU |
| dc.contributor.author |
Андреева Вера Владимировна |
ru_RU |
| dc.contributor.author |
Иванова Елизавета Сергеевна |
ru_RU |
| dc.contributor.author |
Марьясов Максим Александрович |
ru_RU |
| dc.contributor.author |
Насакин Олег Евгеньевич |
ru_RU |
| dc.date.accessioned |
2022-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2022-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2022 |
ru_RU |
| dc.identifier.citation |
Nasakin O. E. New Multifunctional Synthon in Organic Chemistry / O. E. Nasakin, E. S. Ivanova, M. A. Marya-sov, V. V. Andreeva, O. A. Lodochnikova, D. Yu. Grishaev // SSRN.-2022.-P.17 |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=295505 |
ru_RU |
| dc.description.abstract |
SSRN |
ru_RU |
| dc.description.abstract |
“Heptyl” (unsymmetrical dimethylhydrazine - UDMH) is actively used as fuel for rocket engines in many countries around the world. Nonetheless, it constantly loses its properties due to absorption of moisture which cannot be azeotroped. Its long term application is of special concern. UDMH's transportation and processing is complicated since it is an extremely toxic compound of the 1 st hazard class. Its disposal via burning gives much more toxic oxidation products. The safest way to neutralize it is instantaneous interaction with formalin solution to form less toxic 1,1-dimethyl-2-methylenehydrazone (MDH), which is polymerized in an acidic media, and the resulting product is burned forming a huge amount of nitrogen oxides. The purpose of this work is to reveal the synthetic possibilities and practical application of MDH. We would like to pay international chemical community's attention to this extremely promising metastable compound to the purposes of molecular design, pharmaceutical and medicinal chemistry. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
unsymmetrical dimethylhydrazine |
ru_RU |
| dc.subject |
methylene dimethylhydrazone |
ru_RU |
| dc.subject |
tetracyanoethylene |
ru_RU |
| dc.subject |
tetracyanoketones |
ru_RU |
| dc.subject |
Thorp-Ziegler type cyclization |
ru_RU |
| dc.title |
New Multifunctional Synthon in Organic Chemistry |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
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