КФУ. Карточка публикации. The Analytical Capabilities of Electrochemical Sensors Based on Transition Metal Oxide Nanomaterials

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THE ANALYTICAL CAPABILITIES OF ELECTROCHEMICAL SENSORS BASED ON TRANSITION METAL OXIDE NANOMATERIALS

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2023

Язык

английский

Авторы, сотрудники КФУ

Зиятдинова Гузель Камилевна, автор

Авторы, аспиранты КФУ

Гимадутдинова Лилия Тимуровна, автор

Якупова Эльвира Наилевна, автор

Авторы, студенты КФУ

Антонова Татьяна Сергеевна, автор

Григорьева Ирина Олеговна, автор

Библиографическое описание на языке оригинала

Ziyatdinova, G. The analytical capabilities of electrochemical sensors based on transition metal oxide nanomaterials / G. Ziyatdinova, L. Gimadutdinova, T. Antonova, I. Grigoreva, E. Yakupova // Eng. Proc. - 2023. - V. 48. - № 1. - Article 13. - 7 p.

Аннотация

Voltammetric sensors based on CeO2, SnO2, CeO2?Fe2O3 nanoparticles (NPs) and MnO2 nanorods (NRs) were developed for the quantification of various organic substances. Surfactant media were applied as dispersive agents for metal oxide nanomaterials, providing a high stability of the dispersions after sonication and a decrease in the NPs' size, as well as the preconcentration of the target analytes at the sensor surface due to the hydrophobic interactions between the surfactant and the analyte molecules. Natural phenolics (quercetin, rutin, gallic acid, taxifolin, eugenol, vanillin, and hesperidin), propyl gallate, α-lipoic acid, and synthetic food colorants (tartrazine, brilliant blue FCF, and sudan I) were studied as analytes. The effect of the nature and concentration of the surfactant on the target analyte response was evaluated. Cationic surfactants (cetylpyridinium (CPB) or cetyltriphenylphosphonium bromides (CTPPB)) showed the best effect for the majority of the analytes. Wide linear dynamic ranges and low detection limits were obtained and were improved vs. reported to date. The simultaneous quantification of tartrazine and brilliant blue FCF was achieved with a high selectivity. The practical applicability of the sensors was shown on the real samples and was validated by comparison to independent methods.

Ключевые слова

Electrochemical sensors, voltammetry, chemically modified electrodes, metal oxide nanomaterials, surfactants, antioxidants, food colorants, azo dyes

Название журнала

Engineering Proceedings

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85184658375&doi=10.3390%2fCSAC2023-14916&partnerID=40&md5=9246be80ea52bd6f7ab0140f1afc5cf2

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https://repository.kpfu.ru/?p_id=300055

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Зиятдинова Гузель Камилевна	ru_RU
dc.contributor.author	Антонова Татьяна Сергеевна	ru_RU
dc.contributor.author	Григорьева Ирина Олеговна	ru_RU
dc.contributor.author	Гимадутдинова Лилия Тимуровна	ru_RU
dc.contributor.author	Якупова Эльвира Наилевна	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Ziyatdinova, G. The analytical capabilities of electrochemical sensors based on transition metal oxide nanomaterials / G. Ziyatdinova, L. Gimadutdinova, T. Antonova, I. Grigoreva, E. Yakupova // Eng. Proc. - 2023. - V. 48. - № 1. - Article 13. - 7 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=300055	ru_RU
dc.description.abstract	Engineering Proceedings	ru_RU
dc.description.abstract	Voltammetric sensors based on CeO2, SnO2, CeO2?Fe2O3 nanoparticles (NPs) and MnO2 nanorods (NRs) were developed for the quantification of various organic substances. Surfactant media were applied as dispersive agents for metal oxide nanomaterials, providing a high stability of the dispersions after sonication and a decrease in the NPs' size, as well as the preconcentration of the target analytes at the sensor surface due to the hydrophobic interactions between the surfactant and the analyte molecules. Natural phenolics (quercetin, rutin, gallic acid, taxifolin, eugenol, vanillin, and hesperidin), propyl gallate, α-lipoic acid, and synthetic food colorants (tartrazine, brilliant blue FCF, and sudan I) were studied as analytes. The effect of the nature and concentration of the surfactant on the target analyte response was evaluated. Cationic surfactants (cetylpyridinium (CPB) or cetyltriphenylphosphonium bromides (CTPPB)) showed the best effect for the majority of the analytes. Wide linear dynamic ranges and low detection limits were obtained and were improved vs. reported to date. The simultaneous quantification of tartrazine and brilliant blue FCF was achieved with a high selectivity. The practical applicability of the sensors was shown on the real samples and was validated by comparison to independent methods.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Electrochemical sensors	ru_RU
dc.subject	voltammetry	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	metal oxide nanomaterials	ru_RU
dc.subject	surfactants	ru_RU
dc.subject	antioxidants	ru_RU
dc.subject	food colorants	ru_RU
dc.subject	azo dyes	ru_RU
dc.title	The Analytical Capabilities of Electrochemical Sensors Based on Transition Metal Oxide Nanomaterials	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU