КФУ. Карточка публикации. Green reaction engineering towards an iron-based nanostructured hybrid as an electrocatalyst for oxygen evolution reaction

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GREEN REACTION ENGINEERING TOWARDS AN IRON-BASED NANOSTRUCTURED HYBRID AS AN ELECTROCATALYST FOR OXYGEN EVOLUTION REACTION

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2024

Язык

английский

Авторы, сотрудники КФУ

Вагизов Фарит Габдулхакович, автор

Заиров Рустэм Равилевич, автор

Зиннатуллин Алмаз Линарович, автор

Библиографическое описание на языке оригинала

Dymerska A.G, Wenelska K, Vagizov F, Green reaction engineering towards an iron-based nanostructured hybrid as an electrocatalyst for oxygen evolution reaction//Journal of Materials Chemistry A. - 2024. - Vol.12, Is.26. - p. 16007–16021

Аннотация

Developing robust electrocatalysts based on nonprecious metals with high activity in the sluggish oxygen-evolution reaction (OER) is crucial for achieving large-scale hydrogen production. We present a novel approach to design a molecular iron-based hybrid composed of Fe3O4, Fe, and FeNi3 with a sphere-like structure deposited on a flaky substrate. Our optimized catalyst, denoted as Fe/Ni_450C, demonstrates superior electroactivity with a low overpotential of 307 mV, and a minimal Tafel slope of 42 mV dec−1. The material demonstrates ultra-high durability in a 425 h stability test, retaining 86.80% of initial potential at 10 mA cm−2, and exhibits outstanding resistance to high currents (450 mA). The ex situ XRD, XPS, and Mössbauer spectroscopy analyses shed light on the underlying mechanism. Utilizing low-temperature operational conditions, environmentally friendly substrates, cost-effectiveness, high abundance, and impressive stability at high current density collectively position our findings as a pivotal step toward practical applications in the industry associated with electrochemical water decomposition.

Ключевые слова

oxygen evolution reaction, electrocatalyst, iron-based nanostructured hybrid

Название журнала

Journal of Materials Chemistry A

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85195067041&doi=10.1039%2fd4ta01193g&partnerID=40&md5=79df521d7a517d701ae1eeb3e8f6d87e

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https://repository.kpfu.ru/?p_id=301770

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Вагизов Фарит Габдулхакович	ru_RU
dc.contributor.author	Заиров Рустэм Равилевич	ru_RU
dc.contributor.author	Зиннатуллин Алмаз Линарович	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Dymerska A.G, Wenelska K, Vagizov F, Green reaction engineering towards an iron-based nanostructured hybrid as an electrocatalyst for oxygen evolution reaction//Journal of Materials Chemistry A. - 2024. - Vol.12, Is.26. - p. 16007–16021	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=301770	ru_RU
dc.description.abstract	Journal of Materials Chemistry A	ru_RU
dc.description.abstract	Developing robust electrocatalysts based on nonprecious metals with high activity in the sluggish oxygen-evolution reaction (OER) is crucial for achieving large-scale hydrogen production. We present a novel approach to design a molecular iron-based hybrid composed of Fe3O4, Fe, and FeNi3 with a sphere-like structure deposited on a flaky substrate. Our optimized catalyst, denoted as Fe/Ni_450C, demonstrates superior electroactivity with a low overpotential of 307 mV, and a minimal Tafel slope of 42 mV dec−1. The material demonstrates ultra-high durability in a 425 h stability test, retaining 86.80% of initial potential at 10 mA cm−2, and exhibits outstanding resistance to high currents (450 mA). The ex situ XRD, XPS, and Mössbauer spectroscopy analyses shed light on the underlying mechanism. Utilizing low-temperature operational conditions, environmentally friendly substrates, cost-effectiveness, high abundance, and impressive stability at high current density collectively position our findings as a pivotal step toward practical applications in the industry associated with electrochemical water decomposition.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	oxygen evolution reaction	ru_RU
dc.subject	electrocatalyst	ru_RU
dc.subject	iron-based nanostructured hybrid	ru_RU
dc.title	Green reaction engineering towards an iron-based nanostructured hybrid as an electrocatalyst for oxygen evolution reaction	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU