Форма представления | Статьи в российских журналах и сборниках |
Год публикации | 2024 |
Язык | английский |
|
Гнездилов Олег Иванович, автор
|
Библиографическое описание на языке оригинала |
Кучкаев Айдар М., Ковалентная функционализация малослойного черного фосфора комплексом [NiBr2(phen)], где phen – 1,10-фенантролин/ Кучкаев Айрат М., Сухов А.В., Сапарина С.В., Гнездилов О.И., Климовицкий А.Е., Зиганшина С.А., Низамеев И.Р., Файзуллин Б.А., Синяшин О.Г., Яхваров Д.Г.// ЖСХ. – 2024. - T.65. - №4. -P.124527 |
Аннотация |
A 2D material few-layer black phosphorus (FLBP) has promising applications in various fields of chemistry and physics due to its unique electronic and optical properties. Chemical functionalization of the FLBP surface is an effective strategy for improving the oxidative stability of the material, tuning its intrinsic properties or endowing it with new properties. The present work proposes an approach to the immobilization of the [NiBr2(phen)] complex (phen = 1, 10-phenanthroline) on the FLBP surface via covalent functionalization of FLBP with 1,10-phenanthroline and subsequent complexation with NiBr2. The obtained FLBP-based materials functionalized by the [NiBr2(phen)] complex were characterized by a set of physicochemical methods such as transmission electron microscopy, atomic force microscopy, solid-state NMR, energy-dispersive spectroscopy, Raman spectroscopy, and IR spectroscopy. |
Ключевые слова |
black phosphorus, phosphorene, covalent functionalization, diimine ligands, 1,10-phenanthroline, nickel complexes, diazo compounds |
Название журнала |
J STRUCT CHEM+
|
URL |
http:// doi:10.1134/S0022476624040012 |
Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=303881 |
Файлы ресурса | |
|
Полная запись метаданных |
Поле DC |
Значение |
Язык |
dc.contributor.author |
Гнездилов Олег Иванович |
ru_RU |
dc.date.accessioned |
2024-01-01T00:00:00Z |
ru_RU |
dc.date.available |
2024-01-01T00:00:00Z |
ru_RU |
dc.date.issued |
2024 |
ru_RU |
dc.identifier.citation |
Кучкаев Айдар М., Ковалентная функционализация малослойного черного фосфора комплексом [NiBr2(phen)], где phen – 1,10-фенантролин/ Кучкаев Айрат М., Сухов А.В., Сапарина С.В., Гнездилов О.И., Климовицкий А.Е., Зиганшина С.А., Низамеев И.Р., Файзуллин Б.А., Синяшин О.Г., Яхваров Д.Г.// ЖСХ. – 2024. - T.65. - №4. -P.124527 |
ru_RU |
dc.identifier.uri |
https://repository.kpfu.ru/?p_id=303881 |
ru_RU |
dc.description.abstract |
J STRUCT CHEM+ |
ru_RU |
dc.description.abstract |
A 2D material few-layer black phosphorus (FLBP) has promising applications in various fields of chemistry and physics due to its unique electronic and optical properties. Chemical functionalization of the FLBP surface is an effective strategy for improving the oxidative stability of the material, tuning its intrinsic properties or endowing it with new properties. The present work proposes an approach to the immobilization of the [NiBr2(phen)] complex (phen = 1, 10-phenanthroline) on the FLBP surface via covalent functionalization of FLBP with 1,10-phenanthroline and subsequent complexation with NiBr2. The obtained FLBP-based materials functionalized by the [NiBr2(phen)] complex were characterized by a set of physicochemical methods such as transmission electron microscopy, atomic force microscopy, solid-state NMR, energy-dispersive spectroscopy, Raman spectroscopy, and IR spectroscopy. |
ru_RU |
dc.language.iso |
ru |
ru_RU |
dc.subject |
black phosphorus |
ru_RU |
dc.subject |
phosphorene |
ru_RU |
dc.subject |
covalent functionalization |
ru_RU |
dc.subject |
diimine ligands |
ru_RU |
dc.subject |
1 |
ru_RU |
dc.subject |
10-phenanthroline |
ru_RU |
dc.subject |
nickel complexes |
ru_RU |
dc.subject |
diazo compounds |
ru_RU |
dc.title |
Journal of Structural Chemistry |
ru_RU |
dc.type |
Статьи в российских журналах и сборниках |
ru_RU |
|