КФУ. Карточка публикации. New Promoters Derived from Amino Acids and Citric Acid for the Efficient Storage of Methane As Gas Hydrates

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NEW PROMOTERS DERIVED FROM AMINO ACIDS AND CITRIC ACID FOR THE EFFICIENT STORAGE OF METHANE AS GAS HYDRATES

Форма представления

Статьи в российских журналах и сборниках

Год публикации

2024

Язык

русский

Авторы, сотрудники КФУ

Казакова Полина Юрьевна, автор

Библиографическое описание на языке оригинала

Gainullin S. E. New Promoters Derived from Amino Acids and Citric Acid for the Efficient Storage of Methane As Gas Hydrates / S. E. Gainullin, P. Y. Kazakova, R. S. Pavelyev, Y. F. Chirkova, M. E. Semenov, M. A. Varfolomeev // Chemistry and Technology of Fuels and Oils. – 2024. – P. 848-854.

Аннотация

In this work, we studied new citric acid derivatives of some amino acids, which improve the formation kinetics of methane hydrate at low concentrations. These compounds hold potential as efficient promoters of hydrate formation with the advantage that they do not foam upon release of the gas from the hydrates. The modification of the amino acids by citric acid enhances their efficiency as kinetic promoters of methane hydrate formation relative to the unmodified amino acids. This leads to shortening of the induction time and time to achieve maximal conversion of water to hydrate as well as to enhancing the methane uptake. The amide of norleucine and citric acid enhances the conversion of water to hydrate relative to the unmodified amino acid. For 0.05 mass % solutions, the conversion is increased by 5% to 89%, which corresponds to the absorption of 0.148 mole of methane per 1 mole of water. This modification of norleucine also leads to shortening of the induction time by a factor of 1.6 and of the time to reach maximal conversion by a factor of 2.8 relative to unmodified norleucine.

Ключевые слова

gas hydrates, methane hydrates, natural gas storage, hydrate formation promotion, amino acids, citric acid, kinetic promoters, methane hydrate formation promoters

Название журнала

Химия и технология топлив и масел

URL

https://link.springer.com/article/10.1007/s10553-024-01745-3

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https://repository.kpfu.ru/?p_id=309423

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Казакова Полина Юрьевна	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Gainullin S. E. New Promoters Derived from Amino Acids and Citric Acid for the Efficient Storage of Methane As Gas Hydrates / S. E. Gainullin, P. Y. Kazakova, R. S. Pavelyev, Y. F. Chirkova, M. E. Semenov, M. A. Varfolomeev // Chemistry and Technology of Fuels and Oils. – 2024. – P. 848-854.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=309423	ru_RU
dc.description.abstract	Химия и технология топлив и масел	ru_RU
dc.description.abstract	In this work, we studied new citric acid derivatives of some amino acids, which improve the formation kinetics of methane hydrate at low concentrations. These compounds hold potential as efficient promoters of hydrate formation with the advantage that they do not foam upon release of the gas from the hydrates. The modification of the amino acids by citric acid enhances their efficiency as kinetic promoters of methane hydrate formation relative to the unmodified amino acids. This leads to shortening of the induction time and time to achieve maximal conversion of water to hydrate as well as to enhancing the methane uptake. The amide of norleucine and citric acid enhances the conversion of water to hydrate relative to the unmodified amino acid. For 0.05 mass % solutions, the conversion is increased by 5% to 89%, which corresponds to the absorption of 0.148 mole of methane per 1 mole of water. This modification of norleucine also leads to shortening of the induction time by a factor of 1.6 and of the time to reach maximal conversion by a factor of 2.8 relative to unmodified norleucine.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	gas hydrates	ru_RU
dc.subject	methane hydrates	ru_RU
dc.subject	natural gas storage	ru_RU
dc.subject	hydrate formation promotion	ru_RU
dc.subject	amino acids	ru_RU
dc.subject	citric acid	ru_RU
dc.subject	kinetic promoters	ru_RU
dc.subject	methane hydrate formation promoters	ru_RU
dc.title	New Promoters Derived from Amino Acids and Citric Acid for the Efficient Storage of Methane As Gas Hydrates	ru_RU
dc.type	Статьи в российских журналах и сборниках	ru_RU