КФУ. Карточка публикации. Pressure induced ferromagnetism and structural phase transition in the van der Waals material CrCl3

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PRESSURE INDUCED FERROMAGNETISM AND STRUCTURAL PHASE TRANSITION IN THE VAN DER WAALS MATERIAL CRCL3

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2025

Язык

английский

Авторы, сотрудники КФУ

Белушкин Александр Владиславович, автор

Лис Ольга , автор

Другие авторы

Агафонов Сергей Сергеевич, автор

Борисова Полина Алексеевна, автор

Зель Иван , автор

Кичанов Сергей Евгеньевич, автор

Козленко Денис Петрович, автор

Лукин Евгений , автор

Савенко Борис Николаевич, автор

Библиографическое описание на языке оригинала

Lis O. N. Pressure induced ferromagnetism and structural phase transition in the van der Waals material CrCl3 / O.N. Lis, D.P. Kozlenko, E.V. Lukin, S.E. Kichanov, I.Yu. Zel, A.V. Belushkin, S.S. Agafonov, P.A. Borisova, B.N. Savenko // Phys. Rev. B. - 2025. - v.112. - P. 104105-1 -104115-11.

Аннотация

The crystal and magnetic structures of van der Waals layered antiferromagnet CrCl3 have been studied using x-ray and neutron powder diffraction at pressures up to 15 GPa at ambient temperature and up to 2 GPa in a temperature range 7–300 K, respectively. The vibrational properties of CrCl3 were studied using Raman spectroscopy at pressures up to 28 GPa at ambient temperature. Application of high pressure leads to a gradual structural phase transition from the monoclinic C2/m to rhombohedral R¯3 structure developed in the pressure range of 1–6 GPa at ambient temperature. It is accompanied by anomalies in the pressure behavior of lattice parameters, unit cell volume, and vibrational modes. Upon compression above 1 GPa at low temperatures, the initial A-type antiferromagnetic state becomes suppressed, and the ferromagnetic state is formed below Curie temperature TC ∼ 19 K. The microscopic nature of the pressure-induced AFM–FM magnetic phase transition in bulk CrCl3 is different from those found in bilayer CrI3. These findings clarify, in detail, a response of structural andmagnetic states in a model CrCl3 system with the AFM ground state on variation of thermodynamic parameters and provide important information for further development of theoretical models describing physical properties of chromium trihalides and related van der Waals materials in bulk and few-layered forms.

Ключевые слова

crystal structure, magnetic structure, high pressure, neutron diffraction

Название журнала

PHYS REV B

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https://repository.kpfu.ru/?p_id=317323

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Белушкин Александр Владиславович	ru_RU
dc.contributor.author	Лис Ольга	ru_RU
dc.contributor.author	Агафонов Сергей Сергеевич	ru_RU
dc.contributor.author	Борисова Полина Алексеевна	ru_RU
dc.contributor.author	Зель Иван	ru_RU
dc.contributor.author	Кичанов Сергей Евгеньевич	ru_RU
dc.contributor.author	Козленко Денис Петрович	ru_RU
dc.contributor.author	Лукин Евгений	ru_RU
dc.contributor.author	Савенко Борис Николаевич	ru_RU
dc.date.accessioned	2025-01-01T00:00:00Z	ru_RU
dc.date.available	2025-01-01T00:00:00Z	ru_RU
dc.date.issued	2025	ru_RU
dc.identifier.citation	Lis O. N. Pressure induced ferromagnetism and structural phase transition in the van der Waals material CrCl3 / O.N. Lis, D.P. Kozlenko, E.V. Lukin, S.E. Kichanov, I.Yu. Zel, A.V. Belushkin, S.S. Agafonov, P.A. Borisova, B.N. Savenko // Phys. Rev. B. - 2025. - v.112. - P. 104105-1 -104115-11.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=317323	ru_RU
dc.description.abstract	PHYS REV B	ru_RU
dc.description.abstract	The crystal and magnetic structures of van der Waals layered antiferromagnet CrCl3 have been studied using x-ray and neutron powder diffraction at pressures up to 15 GPa at ambient temperature and up to 2 GPa in a temperature range 7–300 K, respectively. The vibrational properties of CrCl3 were studied using Raman spectroscopy at pressures up to 28 GPa at ambient temperature. Application of high pressure leads to a gradual structural phase transition from the monoclinic C2/m to rhombohedral R¯3 structure developed in the pressure range of 1–6 GPa at ambient temperature. It is accompanied by anomalies in the pressure behavior of lattice parameters, unit cell volume, and vibrational modes. Upon compression above 1 GPa at low temperatures, the initial A-type antiferromagnetic state becomes suppressed, and the ferromagnetic state is formed below Curie temperature TC ∼ 19 K. The microscopic nature of the pressure-induced AFM–FM magnetic phase transition in bulk CrCl3 is different from those found in bilayer CrI3. These findings clarify, in detail, a response of structural andmagnetic states in a model CrCl3 system with the AFM ground state on variation of thermodynamic parameters and provide important information for further development of theoretical models describing physical properties of chromium trihalides and related van der Waals materials in bulk and few-layered forms.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	crystal structure	ru_RU
dc.subject	magnetic structure	ru_RU
dc.subject	high pressure	ru_RU
dc.subject	neutron diffraction	ru_RU
dc.title	Pressure induced ferromagnetism and structural phase transition in the van der Waals material CrCl3	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU