| Форма представления | Статьи в зарубежных журналах и сборниках |
| Год публикации | 2025 |
| Язык | английский |
|
Болматенков Дмитрий Николаевич, автор
Низамов Ильяс Ильнарович, автор
Нотфуллин Айрат Альбертович, автор
Соколов Андрей Анатольевич, автор
Соломонов Борис Николаевич, автор
Ягофаров Михаил Искандерович, автор
|
| Библиографическое описание на языке оригинала |
Bolmatenkov D.N, Nizamov I.I, Sokolov A.A, Notfullin A.A., Solomonov B.N., Yagofarov M.I. Polymorphism and Phase-Transition Thermodynamic Properties of Phenazone (Antipyrine) // Molecules. - 2025. - Vol.30, Is.13. - Art. №2814. |
| Аннотация |
In this work, detailed information on the phase-transition thermodynamics of the analgesic and antipyretic drug phenazone, also known as antipyrine, is reported. It was found that the compound forms two polymorphs. Fusion thermodynamics of both forms was studied between 298.15 K and Tm using the combination of differential scanning calorimetry and solution calorimetry. The vapor pressures above crystalline and liquid phenazone were measured for the first time using thermogravimetry-fast scanning calorimetry technique. These studies were complemented by computation of the ideal gas entropy and heat capacity and by measurements of the condensed phase heat capacities. On the basis of experiments performed, we derived sublimation and vaporization enthalpies and vapor pressure above liquid and both crystalline modifications of phenazone in a wide range of temperatures. |
| Ключевые слова |
antipyrine, differential scanning calorimetry, fast scanning calorimetry, fusion enthalpy, heat capacity, phenazone, polymorphism, solution calorimetry, vapor pressure |
| Название журнала |
Molecules
|
| URL |
https://www.scopus.com/inward/record.uri?eid=2-s2.0-105010233924&doi=10.3390%2fmolecules30132814&partnerID=40&md5=b0d13d21b61b46d01b81107e6583386a |
| Пожалуйста, используйте этот идентификатор, чтобы цитировать или ссылаться на эту карточку |
https://repository.kpfu.ru/?p_id=319453 |
Полная запись метаданных  |
| Поле DC |
Значение |
Язык |
| dc.contributor.author |
Болматенков Дмитрий Николаевич |
ru_RU |
| dc.contributor.author |
Низамов Ильяс Ильнарович |
ru_RU |
| dc.contributor.author |
Нотфуллин Айрат Альбертович |
ru_RU |
| dc.contributor.author |
Соколов Андрей Анатольевич |
ru_RU |
| dc.contributor.author |
Соломонов Борис Николаевич |
ru_RU |
| dc.contributor.author |
Ягофаров Михаил Искандерович |
ru_RU |
| dc.date.accessioned |
2025-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2025-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2025 |
ru_RU |
| dc.identifier.citation |
Bolmatenkov D.N, Nizamov I.I, Sokolov A.A, Notfullin A.A., Solomonov B.N., Yagofarov M.I. Polymorphism and Phase-Transition Thermodynamic Properties of Phenazone (Antipyrine) // Molecules. - 2025. - Vol.30, Is.13. - Art. №2814. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/?p_id=319453 |
ru_RU |
| dc.description.abstract |
Molecules |
ru_RU |
| dc.description.abstract |
In this work, detailed information on the phase-transition thermodynamics of the analgesic and antipyretic drug phenazone, also known as antipyrine, is reported. It was found that the compound forms two polymorphs. Fusion thermodynamics of both forms was studied between 298.15 K and Tm using the combination of differential scanning calorimetry and solution calorimetry. The vapor pressures above crystalline and liquid phenazone were measured for the first time using thermogravimetry-fast scanning calorimetry technique. These studies were complemented by computation of the ideal gas entropy and heat capacity and by measurements of the condensed phase heat capacities. On the basis of experiments performed, we derived sublimation and vaporization enthalpies and vapor pressure above liquid and both crystalline modifications of phenazone in a wide range of temperatures. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
antipyrine |
ru_RU |
| dc.subject |
differential scanning calorimetry |
ru_RU |
| dc.subject |
fast scanning calorimetry |
ru_RU |
| dc.subject |
fusion enthalpy |
ru_RU |
| dc.subject |
heat capacity |
ru_RU |
| dc.subject |
phenazone |
ru_RU |
| dc.subject |
polymorphism |
ru_RU |
| dc.subject |
solution calorimetry |
ru_RU |
| dc.subject |
vapor pressure |
ru_RU |
| dc.title |
Polymorphism and Phase-Transition Thermodynamic Properties of Phenazone (Antipyrine) |
ru_RU |
| dc.type |
Статьи в зарубежных журналах и сборниках |
ru_RU |
|
EN 
中文 
ES 
Карта сайта
