КФУ. Карточка публикации. Spectroscopic techniques and hindered molecular motion

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SPECTROSCOPIC TECHNIQUES AND HINDERED MOLECULAR MOTION

Форма представления

Зарубежные монографии

Год публикации

2012

Язык

английский

Авторы, сотрудники КФУ

Баширов Фэрид Исрафилович, автор

Библиографическое описание на языке оригинала

Ferid Bashirov. Spectroscopic techniques and hindered molecular motion. CRC Press, London – New York. – 2012. – 165 p.

Аннотация

The united theoretical approach based on the extended angular jump model for the hindered molecular motion is used in order to describe the molecular spectra in single crystals, powders and liquids. The consecutive derivation of new analytical expressions describing quantitatively relative NMR-relaxation rates and intensities of homogeneously broadened spectral lines observed by dielectric, infrared, Raman, Rayleigh, and incoherent neutron spectroscopy techniques is presented. Accounting for two point symmetry groups, the symmetry group of the hindered molecular motion and that of the molecule site, distortion inclusively, enhances the power of the theory. The hindered molecular motion adapted to the crystallographic point symmetry groups handles the angular autocorrelation functions and, hence, the transformation property of molecular variables. Two dynamical quantities of the model, the symmetrized correlation times and the dynamical weights of hindered molecular motion states, expl

Ключевые слова

Hindered molecular motion, molecular spectroscopy, group theory, condensed molecular media, angular autocorrelation function

URL

http://www.taylorandfrancis.com/books/details/9781439870839/

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https://repository.kpfu.ru/?p_id=73292

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Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Баширов Фэрид Исрафилович	ru_RU
dc.date.accessioned	2012-01-01T00:00:00Z	ru_RU
dc.date.available	2012-01-01T00:00:00Z	ru_RU
dc.date.issued	2012	ru_RU
dc.identifier.citation	Ferid Bashirov. Spectroscopic techniques and hindered molecular motion. CRC Press, London – New York. – 2012. – 165 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=73292	ru_RU
dc.description.abstract	The united theoretical approach based on the extended angular jump model for the hindered molecular motion is used in order to describe the molecular spectra in single crystals, powders and liquids. The consecutive derivation of new analytical expressions describing quantitatively relative NMR-relaxation rates and intensities of homogeneously broadened spectral lines observed by dielectric, infrared, Raman, Rayleigh, and incoherent neutron spectroscopy techniques is presented. Accounting for two point symmetry groups, the symmetry group of the hindered molecular motion and that of the molecule site, distortion inclusively, enhances the power of the theory. The hindered molecular motion adapted to the crystallographic point symmetry groups handles the angular autocorrelation functions and, hence, the transformation property of molecular variables. Two dynamical quantities of the model, the symmetrized correlation times and the dynamical weights of hindered molecular motion states, expl	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Hindered molecular motion	ru_RU
dc.subject	molecular spectroscopy	ru_RU
dc.subject	group theory	ru_RU
dc.subject	condensed molecular media	ru_RU
dc.subject	angular autocorrelation function	ru_RU
dc.title	Spectroscopic techniques and hindered molecular motion	ru_RU
dc.type	Зарубежные монографии	ru_RU