КФУ. Карточка публикации. Crystal structure of phosphonium carboxylate complexes. The role of the metal coordination geometry, ligand conformation and hydrogen bonding

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CRYSTAL STRUCTURE OF PHOSPHONIUM CARBOXYLATE COMPLEXES. THE ROLE OF THE METAL COORDINATION GEOMETRY, LIGAND CONFORMATION AND HYDROGEN BONDING

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2014

Язык

русский

Авторы, сотрудники КФУ

Бахтиярова Юлия Валерьевна, автор

Галкин Владимир Иванович, автор

Галкина Ирина Васильевна, автор

Катаева Ольга Николаевна, автор

Стахеев Виталий Владимирович, автор

Туфатуллин Артем Игоревич, автор

Черкасов Рафаэль Асхатович, автор

Чубукаева Динара Рашитовна, автор

Авторы, аспиранты КФУ

Сираева Динара Рашитовна, автор

Библиографическое описание на языке оригинала

I.Galkina, A.Tufatullin, D.Krivolapov, Yu. Bakhtiyarova, D. Chubukaeva, V.Stakheev, V.Galkin, R.Cherkasov, B.Buchnerc, O.Kataeva,Crystal structure of phosphonium carboxylate complexes. The role of the metal coordination geometry, ligand conformation and hydrogen bonding, CrystEngComm, 2014, V. 16, P. 9010-9024. DOI: 10.1039/C4CE01361A

Аннотация

A series of new mononuclear and heteronuclear complexes of carboxylate phosphonium betaines with biologically important metals were obtained in aqueous media at ambient temperature. X-ray single crystal diffraction showed that carboxylate phosphonium betaines exhibit versatile complexation ability, producing monomeric, dimeric, tetrameric homonuclear and mixed metal complexes, water playing an important role in crystal formation. The binding mode was found to change in the series of Zn(II), Cd(II), Hg(II) complexes with the increase of the cation radius. In case of α- and β-substituted phosphabetaines the crystallization of various stereoisomers was observed including rare case of co-crystallization of two diastereomers in one crystal.

Ключевые слова

X-ray single crystal diffraction, carboxylate phosphonium betaines, mononuclear and heteronuclear complexes of Zn(II), Cd(II), Hg(II)

Название журнала

CRYSTENGCOMM

URL

http://pubs.rsc.org/en/content/articlelanding/2014/ce/c4ce01361a

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https://repository.kpfu.ru/?p_id=84925

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Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Бахтиярова Юлия Валерьевна	ru_RU
dc.contributor.author	Галкин Владимир Иванович	ru_RU
dc.contributor.author	Галкина Ирина Васильевна	ru_RU
dc.contributor.author	Катаева Ольга Николаевна	ru_RU
dc.contributor.author	Стахеев Виталий Владимирович	ru_RU
dc.contributor.author	Туфатуллин Артем Игоревич	ru_RU
dc.contributor.author	Черкасов Рафаэль Асхатович	ru_RU
dc.contributor.author	Чубукаева Динара Рашитовна	ru_RU
dc.contributor.author	Сираева Динара Рашитовна	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	I.Galkina, A.Tufatullin, D.Krivolapov, Yu. Bakhtiyarova, D. Chubukaeva, V.Stakheev, V.Galkin, R.Cherkasov, B.Buchnerc, O.Kataeva,Crystal structure of phosphonium carboxylate complexes. The role of the metal coordination geometry, ligand conformation and hydrogen bonding, CrystEngComm, 2014, V. 16, P. 9010-9024. DOI: 10.1039/C4CE01361A	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=84925	ru_RU
dc.description.abstract	CRYSTENGCOMM	ru_RU
dc.description.abstract	A series of new mononuclear and heteronuclear complexes of carboxylate phosphonium betaines with biologically important metals were obtained in aqueous media at ambient temperature. X-ray single crystal diffraction showed that carboxylate phosphonium betaines exhibit versatile complexation ability, producing monomeric, dimeric, tetrameric homonuclear and mixed metal complexes, water playing an important role in crystal formation. The binding mode was found to change in the series of Zn(II), Cd(II), Hg(II) complexes with the increase of the cation radius. In case of α- and β-substituted phosphabetaines the crystallization of various stereoisomers was observed including rare case of co-crystallization of two diastereomers in one crystal.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	X-ray single crystal diffraction	ru_RU
dc.subject	carboxylate phosphonium betaines	ru_RU
dc.subject	mononuclear and heteronuclear complexes of Zn(II)	ru_RU
dc.subject	Cd(II)	ru_RU
dc.subject	Hg(II)	ru_RU
dc.title	Crystal structure of phosphonium carboxylate complexes. The role of the metal coordination geometry, ligand conformation and hydrogen bonding	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU