КФУ. Карточка публикации. Direct Guanylation of Amino Groups by Cyanamide in Water: Catalytic Generation and Activation of Unsubstituted Carbodiimide by Scandium (III) Triflate

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DIRECT GUANYLATION OF AMINO GROUPS BY CYANAMIDE IN WATER: CATALYTIC GENERATION AND ACTIVATION OF UNSUBSTITUTED CARBODIIMIDE BY SCANDIUM (III) TRIFLATE

Форма представления

Статьи в зарубежных журналах и сборниках

Год публикации

2014

Авторы, сотрудники КФУ

Курбангалиева Альмира Рафаэловна, автор

Другие авторы

K. Tsubokura; T. Iwata; M. Taichi; K. Fukase; Y. Nakao

Библиографическое описание на языке оригинала

K. Tsubokura, T. Iwata, M. Taichi, A. Kurbangalieva, K. Fukase, Y. Nakao, K. Tanaka. Direct Guanylation of Amino Groups by Cyanamide in Water: Catalytic Generation and Activation of Unsubstituted Carbodiimide by Scandium (III) Triflate // Synlett. 2014. V. 25. № 9. P. 1302-1306.

Аннотация

Guanylation proceeded efficiently upon treatment of the various amines with cyanamide in the presence of catalytic amounts of scandium(III) triflate under mild conditions. The method did not require the guanylation reagents to be preactivated, and the reaction proceeded efficiently in water. The method, therefore, has practical utility for substrates that dissolve only in aqueous solutions, for example, peptides or pharmacologically important compounds.

Ключевые слова

guanylation, Sc(OTf)3, cyanamide, activated carbodiimide

Название журнала

Synlett

URL

https://www.thieme-connect.com/products/ejournals/abstract/10.1055/s-0033-1341080

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https://repository.kpfu.ru/?p_id=87121

Полная запись метаданных

Поле DC	Значение	Язык
dc.contributor.author	Курбангалиева Альмира Рафаэловна	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	K. Tsubokura, T. Iwata, M. Taichi, A. Kurbangalieva, K. Fukase, Y. Nakao, K. Tanaka. Direct Guanylation of Amino Groups by Cyanamide in Water: Catalytic Generation and Activation of Unsubstituted Carbodiimide by Scandium (III) Triflate // Synlett. 2014. V. 25. № 9. P. 1302-1306.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/?p_id=87121	ru_RU
dc.description.abstract	Synlett	ru_RU
dc.description.abstract	Guanylation proceeded efficiently upon treatment of the various amines with cyanamide in the presence of catalytic amounts of scandium(III) triflate under mild conditions. The method did not require the guanylation reagents to be preactivated, and the reaction proceeded efficiently in water. The method, therefore, has practical utility for substrates that dissolve only in aqueous solutions, for example, peptides or pharmacologically important compounds.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	guanylation	ru_RU
dc.subject	Sc(OTf)3	ru_RU
dc.subject	cyanamide	ru_RU
dc.subject	activated carbodiimide	ru_RU
dc.title	Direct Guanylation of Amino Groups by Cyanamide in Water: Catalytic Generation and Activation of Unsubstituted Carbodiimide by Scandium (III) Triflate	ru_RU
dc.type	Статьи в зарубежных журналах и сборниках	ru_RU