KFU. Card publication. Title: Tb(III)-Doped Silica Nanoparticles for Sensing: Effect of Interfacial Interactions on Substrate-Induced Luminescent Response

- RUS
- 中文
- ES

TITLE: TB(III)-DOPED SILICA NANOPARTICLES FOR SENSING: EFFECT OF INTERFACIAL INTERACTIONS ON SUBSTRATE-INDUCED LUMINESCENT RESPONSE

Form of presentation

Articles in Russian journals and collections

Year of publication

2015

��

��

Authors, employees of KFU

Gorbachuk Valeriy Vilenovich, author

Konovalov Aleksandr Ivanovich, author

Other authors

Davydov Nikolay Aleksandrovich, author

Kadirov Marsil Kakhirovich, author

Mustafina Asiya Rafaelevna, author

Nizameev Irek Rashatovich, author

Fedorenko Svetlana Viktorovna, author

Bibliographic description in the original language

Mukhametshina, A. R. Tb(III)-Doped Silica Nanoparticles for Sensing: Effect of Interfacial Interactions on Substrate-Induced Luminescent Response A.R.Mukhametshina, A.R.Mustafina, N.A.Davydov, S.V.Fedorenko, I.R. Nizameev, M.K. Kadirov, V.V.Gorbatchuk, A.I.Konovalov // Langmuir. – 2015. – V. 31, �1. – P. 611-619.

Annotation

The present work introduces the easy modification of the water-in-oil microemulsion procedure aimed at the doping of the Tb(III) complexes within core or shell zones of the silica nanoparticles (SNs), which are designated as core-shell, shell, and core. The dye molecules, chelating ligands, and copper ions were applied as the quenchers of Tb(III)-centered luminescence through dynamic or/and static mechanisms. The binding of the quenchers at the silica/water interface results in the quenching of the Tb(III) complexes within SNs, which, in turn, is greatly dependent on the synthetic procedure. The luminescence of core SNs remains unchanged under the binding of the quenchers at the silica/water interface. The quenching through dynamic mechanism is more significant for core-shell and shell than for core SNs. Thus, both core-shell and shell SNs have enough percentage of the Tb(III) complexes located close to the interface for efficient quenching through the energy transfer. The quenching th

Keywords

RESONANCE ENERGY-TRANSFER, LANTHANIDE LUMINESCENCE, FLUORESCENCE, PROBE, MEMBRANE, COMPLEX, ION, TRIPHOSPHATE, VESICLES, ANTIBODY

The name of the journal

LANGMUIR

URL

http://pubs.acs.org/doi/abs/10.1021/la503074p

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=106002&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gorbachuk Valeriy Vilenovich	ru_RU
dc.contributor.author	Gorbachuk Valeriy Vilenovich	ru_RU
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Davydov Nikolay Aleksandrovich	ru_RU
dc.contributor.author	Kadirov Marsil Kakhirovich	ru_RU
dc.contributor.author	Mustafina Asiya Rafaelevna	ru_RU
dc.contributor.author	Nizameev Irek Rashatovich	ru_RU
dc.contributor.author	Fedorenko Svetlana Viktorovna	ru_RU
dc.date.accessioned	2015-01-01T00:00:00Z	ru_RU
dc.date.available	2015-01-01T00:00:00Z	ru_RU
dc.date.issued	2015	ru_RU
dc.identifier.citation	Mukhametshina, A. R. Tb(III)-Doped Silica Nanoparticles for Sensing: Effect of Interfacial Interactions on Substrate-Induced Luminescent Response A.R.Mukhametshina, A.R.Mustafina, N.A.Davydov, S.V.Fedorenko, I.R. Nizameev, M.K. Kadirov, V.V.Gorbatchuk, A.I.Konovalov // Langmuir. – 2015. – V. 31, �1. – P. 611-619.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=106002&p_lang=2	ru_RU
dc.description.abstract	LANGMUIR	ru_RU
dc.description.abstract	The present work introduces the easy modification of the water-in-oil microemulsion procedure aimed at the doping of the Tb(III) complexes within core or shell zones of the silica nanoparticles (SNs), which are designated as core-shell, shell, and core. The dye molecules, chelating ligands, and copper ions were applied as the quenchers of Tb(III)-centered luminescence through dynamic or/and static mechanisms. The binding of the quenchers at the silica/water interface results in the quenching of the Tb(III) complexes within SNs, which, in turn, is greatly dependent on the synthetic procedure. The luminescence of core SNs remains unchanged under the binding of the quenchers at the silica/water interface. The quenching through dynamic mechanism is more significant for core-shell and shell than for core SNs. Thus, both core-shell and shell SNs have enough percentage of the Tb(III) complexes located close to the interface for efficient quenching through the energy transfer. The quenching th	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	RESONANCE ENERGY-TRANSFER	ru_RU
dc.subject	LANTHANIDE LUMINESCENCE	ru_RU
dc.subject	FLUORESCENCE	ru_RU
dc.subject	PROBE	ru_RU
dc.subject	MEMBRANE	ru_RU
dc.subject	COMPLEX	ru_RU
dc.subject	ION	ru_RU
dc.subject	TRIPHOSPHATE	ru_RU
dc.subject	VESICLES	ru_RU
dc.subject	ANTIBODY	ru_RU
dc.title	Title: Tb(III)-Doped Silica Nanoparticles for Sensing: Effect of Interfacial Interactions on Substrate-Induced Luminescent Response	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU