KFU. Card publication. The Structure of Cationic Polyisoprene: Branching versus Cyclization

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

THE STRUCTURE OF CATIONIC POLYISOPRENE: BRANCHING VERSUS CYCLIZATION

Form of presentation

Articles in international journals and collections

Year of publication

2016

Язык

английский

Authors, employees of KFU

Gnezdilov Oleg Ivanovich, author

Bibliographic description in the original language

Rozentsvet V.A, Kozlov V.G, Korovina N.A, The Structure of Cationic Polyisoprene: Branching versus Cyclization// Macromolecular Chemistry and Physics. - 2016. - Vol.217, Is.16. - P.1860-1867.

Annotation

The structure, molecular weight, and molecular weight distribution (MWD) of polyisoprene fractions, which were obtained during the fraction of polyisoprene with broad MWD (Mw/Mn = 25.6) synthesized with tBuCl/TiCl4 initiating system have been investigated. It is established that chain transfer to polymer leading to branched macromolecules is responsible for the formation of polyisoprene with broad MWD and reduced unsaturation. It is shown for the first time that unsaturation decreased while the content of head and end groups in a single macromolecule increased with increasing molecular weight of polyisoprene fraction. The unsaturated part of the polymer chain consists of presumably trans-1,4-units independently of the molecular weight of polyisoprene fraction

Keywords

structure, molecular weight, polyisoprene fractions, molecular weight distribution, NMR

The name of the journal

Macromolecular Chemistry and Physics

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-84982206020&partnerID=40&md5=9c73a5bde7f8a961d5f531da5258bcb8

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=147473&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gnezdilov Oleg Ivanovich	ru_RU
dc.date.accessioned	2016-01-01T00:00:00Z	ru_RU
dc.date.available	2016-01-01T00:00:00Z	ru_RU
dc.date.issued	2016	ru_RU
dc.identifier.citation	Rozentsvet V.A, Kozlov V.G, Korovina N.A, The Structure of Cationic Polyisoprene: Branching versus Cyclization// Macromolecular Chemistry and Physics. - 2016. - Vol.217, Is.16. - P.1860-1867.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=147473&p_lang=2	ru_RU
dc.description.abstract	Macromolecular Chemistry and Physics	ru_RU
dc.description.abstract	The structure, molecular weight, and molecular weight distribution (MWD) of polyisoprene fractions, which were obtained during the fraction of polyisoprene with broad MWD (Mw/Mn = 25.6) synthesized with tBuCl/TiCl4 initiating system have been investigated. It is established that chain transfer to polymer leading to branched macromolecules is responsible for the formation of polyisoprene with broad MWD and reduced unsaturation. It is shown for the first time that unsaturation decreased while the content of head and end groups in a single macromolecule increased with increasing molecular weight of polyisoprene fraction. The unsaturated part of the polymer chain consists of presumably trans-1,4-units independently of the molecular weight of polyisoprene fraction	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	structure	ru_RU
dc.subject	molecular weight	ru_RU
dc.subject	polyisoprene fractions	ru_RU
dc.subject	molecular weight distribution	ru_RU
dc.subject	NMR	ru_RU
dc.title	The Structure of Cationic Polyisoprene: Branching versus Cyclization	ru_RU
dc.type	Articles in international journals and collections	ru_RU