KFU. Card publication. Reaction of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate.

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FEDERAL UNIVERSITY

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REACTION OF METHYL 2-METHYLIDENE-3-OXOLUP-20(29)-EN-28-OATE WITH TRIPHENYLPHOSPHONIUM TRIFLUOROMETHANESULFONATE.

Form of presentation

Articles in Russian journals and collections

Year of publication

2017

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Authors, employees of KFU

Mironov Vladimir Fedorovich, author

Bibliographic description in the original language

O.V.Tsepaeva, A.V.Nemtarev, V.F.Mironov. Reaction of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate. // Russ. J. Org. Chem. 2017. Vol. 53. No. 4. P. 621-623. Doi 10.1134/S1070428017040212.

Annotation

Phosphorylation of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate in methylene chloride at 20?C afforded 90% of a γ-oxoalkylphosphonium saltcontaining a terpenoid fragment, [28-methoxy-3,28-dioxolup-20(29)-en-2-ylmethyl]triphenylphosphonium trifluoromethanesulfonate, as a mixture of two epimers (2S/2R) at a ratio of 2 : 1.

Keywords

methylidenebetuline, phosphonium salt

The name of the journal

Russian Journal of Organic Chemistry

URL

https://link.springer.com/article/10.1134/S1070428017040212

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=174857&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Mironov Vladimir Fedorovich	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	O.V.Tsepaeva, A.V.Nemtarev, V.F.Mironov. Reaction of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate. // Russ. J. Org. Chem. 2017. Vol. 53. No. 4. P. 621-623. Doi 10.1134/S1070428017040212.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=174857&p_lang=2	ru_RU
dc.description.abstract	Russian Journal of Organic Chemistry	ru_RU
dc.description.abstract	Phosphorylation of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate in methylene chloride at 20?C afforded 90% of a γ-oxoalkylphosphonium saltcontaining a terpenoid fragment, [28-methoxy-3,28-dioxolup-20(29)-en-2-ylmethyl]triphenylphosphonium trifluoromethanesulfonate, as a mixture of two epimers (2S/2R) at a ratio of 2 : 1.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	methylidenebetuline	ru_RU
dc.subject	phosphonium salt	ru_RU
dc.title	Reaction of methyl 2-methylidene-3-oxolup-20(29)-en-28-oate with triphenylphosphonium trifluoromethanesulfonate.	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU