KFU. Card publication. Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB

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SELF-AGGREGATION AND SOLUBILIZING PROPERTIES OF THE SUPRAMOLECULAR SYSTEM BASED ON AZOBENZENESULFONATE CALIX[4]ARENE AND CTAB

Form of presentation

Articles in Russian journals and collections

Year of publication

2017

Authors, employees of KFU

Antipin Igor Sergeevich, author

Akhmetzyanova Zaliya Valievna, author

Konovalov Aleksandr Ivanovich, author

Soloveva Svetlana Evgenevna, author

Other authors

R. R. Kashapov, A. M. Bekmukhametova, L. Ya. Zakharova, E. V. Popova

Authors, postgraduates KFU

Akhmetzyanova Zaliya Valievna, postgraduate kfu

Bibliographic description in the original language

Ruslan R.Kashapov, Alina M.Bekmukhametova, Lucia Ya.Zakharova, Zaliya V. Akhmetzyanova, Elena V.Popova,Svetlana E.Solovieva, Igor S.Antipin, Alexander I.Konovalov, Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB, 2017, v.10 (4-5), p.454-459

Annotation

The intermolecular interaction of azobenzenesulfonate calix[4]arene with cationic surfactant CTAB was studied by a complex of physicochemical methods. The influence of calix[4]arene:CTAB ratio on the form of the aggregates in their mixed composition in the aqueous medium was determined. Single-layer vesicles are formed in the equimolar azobenzenesulfonate calix[4]arene-CTAB mixture. A threefold increase in the proportion of CTAB leads to the enlarge-ment of vesicles, namely, an increase in numbers of bilayers. Spectrophotometry was used to select the conditions for binding of the hydrophobic spectral probe Sudan I by this mixed composition. The fluorescence spectroscopy estab-lishes dependence between the amount of encapsulated Rhodamine B and the size of the vesicle. Thus, the azobenzene-sulfonate calix[4]arene?CTAB system is capable for binding of both hydrophobic and hydrophilic substrates depending on the components ratio.

Keywords

Calixarene, surfactant, Sudan I, Rodamine B, solubilization, aggregation.

The name of the journal

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Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=182385&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Antipin Igor Sergeevich	ru_RU
dc.contributor.author	Akhmetzyanova Zaliya Valievna	ru_RU
dc.contributor.author	Konovalov Aleksandr Ivanovich	ru_RU
dc.contributor.author	Soloveva Svetlana Evgenevna	ru_RU
dc.contributor.author	Akhmetzyanova Zaliya Valievna	ru_RU
dc.date.accessioned	2017-01-01T00:00:00Z	ru_RU
dc.date.available	2017-01-01T00:00:00Z	ru_RU
dc.date.issued	2017	ru_RU
dc.identifier.citation	Ruslan R.Kashapov, Alina M.Bekmukhametova, Lucia Ya.Zakharova, Zaliya V. Akhmetzyanova, Elena V.Popova,Svetlana E.Solovieva, Igor S.Antipin, Alexander I.Konovalov, Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB, 2017, v.10 (4-5), p.454-459	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=182385&p_lang=2	ru_RU
dc.description.abstract	��	ru_RU
dc.description.abstract	The intermolecular interaction of azobenzenesulfonate calix[4]arene with cationic surfactant CTAB was studied by a complex of physicochemical methods. The influence of calix[4]arene:CTAB ratio on the form of the aggregates in their mixed composition in the aqueous medium was determined. Single-layer vesicles are formed in the equimolar azobenzenesulfonate calix[4]arene-CTAB mixture. A threefold increase in the proportion of CTAB leads to the enlarge-ment of vesicles, namely, an increase in numbers of bilayers. Spectrophotometry was used to select the conditions for binding of the hydrophobic spectral probe Sudan I by this mixed composition. The fluorescence spectroscopy estab-lishes dependence between the amount of encapsulated Rhodamine B and the size of the vesicle. Thus, the azobenzene-sulfonate calix[4]arene?CTAB system is capable for binding of both hydrophobic and hydrophilic substrates depending on the components ratio.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Calixarene	ru_RU
dc.subject	surfactant	ru_RU
dc.subject	Sudan I	ru_RU
dc.subject	Rodamine B	ru_RU
dc.subject	solubilization	ru_RU
dc.subject	aggregation.	ru_RU
dc.title	Self-Aggregation and Solubilizing Properties of the Supramolecular System Based on Azobenzenesulfonate Calix[4]arene and CTAB	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU