KFU. Card publication. Polymer Degradation and Stability

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

POLYMER DEGRADATION AND STABILITY

Form of presentation

Articles in international journals and collections

Year of publication

2018

Authors, employees of KFU

Varfolomeev Mikhail Alekseevich, author

Farkhadian Abdolreza , author

Authors, postgraduates KFU

Farkhadian Abdolreza , postgraduate kfu

Bibliographic description in the original language

The purpose of this study is to synthesize non-isocyanate poly (ester amide/urethane) networks, based entirely on vegetable oil through a green method, i.e., without solvent and having any rigid and aromatic structures to improve their thermal stability. For this purpose, first, three amines were synthesized from castor oil and oleic acid. Second, carbonated sunflower oil (CSFO) was obtained by reaction of epoxidized sunflower oil with CO2 at atmospheric pressure. In the final step, CSFO easily reacted with bio-based amines by melt-blending without catalyst to give corresponding non-isocyanate polyurethane (NIPU) networks. The Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), X-ray powder diffraction (XRD), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) techniques were applied to characterize the structural, thermal and physical features of NIPU networks. In addition, to determine the envir

Annotation

Polymer Degradation and Stability

Keywords

Non-isocyanate poly (ester amide/urethane) network Vegetable oils Biobased polymers Environment-friendly synthesis Thermal stability Green chemistry

The name of the journal

Polymer Degradation and Stability

Publishing house

Elsevier

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=197821&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Varfolomeev Mikhail Alekseevich	ru_RU
dc.contributor.author	Farkhadian Abdolreza	ru_RU
dc.contributor.author	Farkhadian Abdolreza	ru_RU
dc.date.accessioned	2018-01-01T00:00:00Z	ru_RU
dc.date.available	2018-01-01T00:00:00Z	ru_RU
dc.date.issued	2018	ru_RU
dc.identifier.citation	The purpose of this study is to synthesize non-isocyanate poly (ester amide/urethane) networks, based entirely on vegetable oil through a green method, i.e., without solvent and having any rigid and aromatic structures to improve their thermal stability. For this purpose, first, three amines were synthesized from castor oil and oleic acid. Second, carbonated sunflower oil (CSFO) was obtained by reaction of epoxidized sunflower oil with CO2 at atmospheric pressure. In the final step, CSFO easily reacted with bio-based amines by melt-blending without catalyst to give corresponding non-isocyanate polyurethane (NIPU) networks. The Fourier-transform infrared spectroscopy (FTIR), nuclear magnetic resonance (NMR), X-ray powder diffraction (XRD), differential scanning calorimetry (DSC), dynamic mechanical analysis (DMA) and thermogravimetric analysis (TGA) techniques were applied to characterize the structural, thermal and physical features of NIPU networks. In addition, to determine the envir	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=197821&p_lang=2	ru_RU
dc.description.abstract	Polymer Degradation and Stability	ru_RU
dc.language.iso	ru	ru_RU
dc.publisher	Elsevier	ru_RU
dc.subject		ru_RU
dc.title	Polymer Degradation and Stability	ru_RU
dc.type	Articles in international journals and collections	ru_RU