KFU. Card publication. Structural Diversity of Interaction Products of Mucochloric Acid and its Derivatives with 1,2-Ethanedithiol

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FEDERAL UNIVERSITY

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STRUCTURAL DIVERSITY OF INTERACTION PRODUCTS OF MUCOCHLORIC ACID AND ITS DERIVATIVES WITH 1,2-ETHANEDITHIOL

Form of presentation

Articles in international journals and collections

Year of publication

2010

Authors, employees of KFU

Berdnikov Evgeniy Aleksandrovich, author

Gnezdilov Oleg Ivanovich, author

Kurbangalieva Almira Rafaelovna, author

Chmutova Galina Alekseevna, author

Other authors

Lodochnikova O.A., Litvinov I.A.

Bibliographic description in the original language

Kurbangalieva A.R., Lodochnikova O.A., Devyatova N.F., Berdnikov E.A., Gnezdilov O.V., Litvinov I.A., Chmutova G.A. Structural Diversity of Interaction Products of Mucochloric Acid and its Derivatives with 1,2-Ethanedithiol // Tetrahedron. 2010. V. 66. Issue 52. P. 9945-9953.

Annotation

The synthesis and characterization of previously unknown sulfur-containing products from the reaction of mucochloric acid (3,4-dichloro-5-hydroxy-2(5H)-furanone) and its 5-alkoxy derivatives with 1,2-ethanedithiol is reported. Under basic and acidic conditions both SH-groups of the reagent show nucleophilic activity, leading to the formation of substitution products of different structural types. Novel fused (7-hydroxy-2,3-dihydro[1,4]dithiino[2,3-c]furan-5(7H)-one) and spiro (9-chloro-6-methoxy-7- oxa-1,4-dithiaspiro[4.4]nonan-8-one) bicyclic compounds, as well as various bis-thioethers have been obtained and characterized by NMR spectroscopy and single crystal X-ray diffraction.

Keywords

Mucochloric acid, Lactones, 2(5H)-Furanones, 1,2-Ethanedithiol, Sulfur heterocycles, Diastereomers

The name of the journal

Tetrahedron

URL

http://www.sciencedirect.com/science/article/pii/S0040402010015619

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=23190&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Berdnikov Evgeniy Aleksandrovich	ru_RU
dc.contributor.author	Gnezdilov Oleg Ivanovich	ru_RU
dc.contributor.author	Kurbangalieva Almira Rafaelovna	ru_RU
dc.contributor.author	Chmutova Galina Alekseevna	ru_RU
dc.date.accessioned	2010-01-01T00:00:00Z	ru_RU
dc.date.available	2010-01-01T00:00:00Z	ru_RU
dc.date.issued	2010	ru_RU
dc.identifier.citation	Kurbangalieva A.R., Lodochnikova O.A., Devyatova N.F., Berdnikov E.A., Gnezdilov O.V., Litvinov I.A., Chmutova G.A. Structural Diversity of Interaction Products of Mucochloric Acid and its Derivatives with 1,2-Ethanedithiol // Tetrahedron. 2010. V. 66. Issue 52. P. 9945-9953.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=23190&p_lang=2	ru_RU
dc.description.abstract	Tetrahedron	ru_RU
dc.description.abstract	The synthesis and characterization of previously unknown sulfur-containing products from the reaction of mucochloric acid (3,4-dichloro-5-hydroxy-2(5H)-furanone) and its 5-alkoxy derivatives with 1,2-ethanedithiol is reported. Under basic and acidic conditions both SH-groups of the reagent show nucleophilic activity, leading to the formation of substitution products of different structural types. Novel fused (7-hydroxy-2,3-dihydro[1,4]dithiino[2,3-c]furan-5(7H)-one) and spiro (9-chloro-6-methoxy-7- oxa-1,4-dithiaspiro[4.4]nonan-8-one) bicyclic compounds, as well as various bis-thioethers have been obtained and characterized by NMR spectroscopy and single crystal X-ray diffraction.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Mucochloric acid	ru_RU
dc.subject	Lactones	ru_RU
dc.subject	2(5H)-Furanones	ru_RU
dc.subject	1	ru_RU
dc.subject	2-Ethanedithiol	ru_RU
dc.subject	Sulfur heterocycles	ru_RU
dc.subject	Diastereomers	ru_RU
dc.title	Structural Diversity of Interaction Products of Mucochloric Acid and its Derivatives with 1,2-Ethanedithiol	ru_RU
dc.type	Articles in international journals and collections	ru_RU