KFU. Card publication. 3,28-диацетоксилуп-20(29)-ен-30-овая кислота и ее ω-бромалкиловые эфиры

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

3,28-ДИАЦЕТОКСИЛУП-20(29)-ЕН-30-ОВАЯ КИСЛОТА И ЕЕ ω-БРОМАЛКИЛОВЫЕ ЭФИРЫ

Form of presentation

Articles in Russian journals and collections

Year of publication

2020

Язык

русский

Authors, employees of KFU

Antipin Igor Sergeevich, author

Gnezdilov Oleg Ivanovich, author

Idrisova Leysan Radikovna, author

Mironov Vladimir Fedorovich, author

Nemtarev Andrey Vladimirovich, author

Ponomarev Denis Vyacheslavovich, author

Cepaeva Olga Viktorovna, author

Authors, postgraduates KFU

Ponomarev Denis Vyacheslavovich, postgraduate kfu

Bibliographic description in the original language

Ponomarev, D. V. 3,28-diacetoksilup-20(29)-en-30-ovaya kislota i ee ω-bromalkilovye efiry / D. V. Ponomarev, L. R. Grigoreva, A. V. Nemtarev, O. V. Cepaeva, V. F. Mironov, O. I. Gnezdilov, I. S. Antipin // Zhurn. organ. khimii. - 2020. - T. 56, № 4. - S.584-590.

Annotation

A convenient procedure has been developed for the synthesis of 3β,28-diacetoxylup-20(29)-en-30- oic acid via oxidation of 3β,28-di-O-acetylbetulin with selenium dioxide in aqueous ethanol on heating, followed by oxidation of 3β,28-diacetoxylup-20(29)-en-30-al thus formed with sodium chlorite in tert-butyl alcohol. The alkylation of 3β,28-diacetoxylup-20(29)-en-30-oic acid with 1,3-dibrompropane and 1,5-dibromopentane in boiling acetonitrile in the presence of potassium carbonate afforded the corresponding ω-bromoalkyl esters in high yields.

Keywords

лупановые тритерпеноиды, бетулин, аллильное окисление, галогеналкиловые эфиры, акцептор Михаэля

The name of the journal

Журнал органической химии

URL

https://www.elibrary.ru/item.asp?id=42644594

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=234089&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Antipin Igor Sergeevich	ru_RU
dc.contributor.author	Gnezdilov Oleg Ivanovich	ru_RU
dc.contributor.author	Idrisova Leysan Radikovna	ru_RU
dc.contributor.author	Mironov Vladimir Fedorovich	ru_RU
dc.contributor.author	Nemtarev Andrey Vladimirovich	ru_RU
dc.contributor.author	Ponomarev Denis Vyacheslavovich	ru_RU
dc.contributor.author	Cepaeva Olga Viktorovna	ru_RU
dc.contributor.author	Ponomarev Denis Vyacheslavovich	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Пономарев, Д. В. 3,28-диацетоксилуп-20(29)-ен-30-овая кислота и ее ω-бромалкиловые эфиры / Д. В. Пономарев, Л. Р. Григорьева, А. В. Немтарев, О. В. Цепаева, В. Ф. Миронов, О. И. Гнездилов, И. С. Антипин // Журн. орган. химии. - 2020. - Т. 56, № 4. - С.584-590.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=234089&p_lang=2	ru_RU
dc.description.abstract	Журнал органической химии	ru_RU
dc.description.abstract	A convenient procedure has been developed for the synthesis of 3β,28-diacetoxylup-20(29)-en-30- oic acid via oxidation of 3β,28-di-O-acetylbetulin with selenium dioxide in aqueous ethanol on heating, followed by oxidation of 3β,28-diacetoxylup-20(29)-en-30-al thus formed with sodium chlorite in tert-butyl alcohol. The alkylation of 3β,28-diacetoxylup-20(29)-en-30-oic acid with 1,3-dibrompropane and 1,5-dibromopentane in boiling acetonitrile in the presence of potassium carbonate afforded the corresponding ω-bromoalkyl esters in high yields.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	лупановые тритерпеноиды	ru_RU
dc.subject	бетулин	ru_RU
dc.subject	аллильное окисление	ru_RU
dc.subject	галогеналкиловые эфиры	ru_RU
dc.subject	акцептор Михаэля	ru_RU
dc.title	3,28-диацетоксилуп-20(29)-ен-30-овая кислота и ее ω-бромалкиловые эфиры	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU