KFU. Card publication. Self-diffusion in ionic liquids with nitrate anion: Effects of confinement between glass plates and static magnetic field

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SELF-DIFFUSION IN IONIC LIQUIDS WITH NITRATE ANION: EFFECTS OF CONFINEMENT BETWEEN GLASS PLATES AND STATIC MAGNETIC FIELD

Form of presentation

Articles in international journals and collections

Year of publication

2020

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Authors, employees of KFU

Gnezdilov Oleg Ivanovich, author

Filippov Andrey Vasilevich, author

Bibliographic description in the original language

Filippov A, Antzutkin O.N, Gimatdinov R, Self-diffusion in ionic liquids with nitrate anion: Effects of confinement between glass plates and static magnetic field//Journal of Molecular Liquids. - 2020. - Vol.312, Is..113404., P1-5.

Annotation

Alkylammonium nitrate protic ionic liquids (ILs), when placed between flat polar borosilicate glass plates, have demonstrated enhanced diffusivity and the gradual decrease of diffusivity after exposure to an external static magnetic field (Filippov et al., 2018). This phenomenon has been explained by phase transformations taking place in the ILs. In this study,we observed similar processes occurring in systems preparedwith ethylammonium nitrate confined between quartz plates. A higher content of silicon oxide in the plates does not significantly alter the phenomenon previously found in the system prepared with borosilicate glass plates. For the first time, we have observed similar effects of confinement and magnetic field on the aprotic IL, 1‑ethyl‑3‑methylimidazolium nitrate. Substitution of the ethylammonium cation with a 1‑ethyl‑3‑methylimidazolium cation slows down the kinetics and increases magnitude of the processes occurring in the IL exposed to a magnetic field. We suggested that the main factor determining these effects is the presence and modification of the hydrogen-bonding network in the studied protic and aprotic ILs. The process of inverse phase transformation for the confined ethylammonium nitrate after removing the sample from the magnetic field was observed and analysed.

Keywords

protic ionic liquids, polar borosilicate glass plates, static magnetic field, phase transformations, ethylammonium nitrate, hydrogen-bonding network, diffusion

The name of the journal

Journal of Molecular Liquids

URL

https://doi.org/10.1016/j.molliq.2020.113404

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=235923&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gnezdilov Oleg Ivanovich	ru_RU
dc.contributor.author	Filippov Andrey Vasilevich	ru_RU
dc.date.accessioned	2020-01-01T00:00:00Z	ru_RU
dc.date.available	2020-01-01T00:00:00Z	ru_RU
dc.date.issued	2020	ru_RU
dc.identifier.citation	Filippov A, Antzutkin O.N, Gimatdinov R, Self-diffusion in ionic liquids with nitrate anion: Effects of confinement between glass plates and static magnetic field//Journal of Molecular Liquids. - 2020. - Vol.312, Is..113404., P1-5.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=235923&p_lang=2	ru_RU
dc.description.abstract	Journal of Molecular Liquids	ru_RU
dc.description.abstract	Alkylammonium nitrate protic ionic liquids (ILs), when placed between flat polar borosilicate glass plates, have demonstrated enhanced diffusivity and the gradual decrease of diffusivity after exposure to an external static magnetic field (Filippov et al., 2018). This phenomenon has been explained by phase transformations taking place in the ILs. In this study,we observed similar processes occurring in systems preparedwith ethylammonium nitrate confined between quartz plates. A higher content of silicon oxide in the plates does not significantly alter the phenomenon previously found in the system prepared with borosilicate glass plates. For the first time, we have observed similar effects of confinement and magnetic field on the aprotic IL, 1‑ethyl‑3‑methylimidazolium nitrate. Substitution of the ethylammonium cation with a 1‑ethyl‑3‑methylimidazolium cation slows down the kinetics and increases magnitude of the processes occurring in the IL exposed to a magnetic field. We suggested that the main factor determining these effects is the presence and modification of the hydrogen-bonding network in the studied protic and aprotic ILs. The process of inverse phase transformation for the confined ethylammonium nitrate after removing the sample from the magnetic field was observed and analysed.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	protic ionic liquids	ru_RU
dc.subject	polar borosilicate glass plates	ru_RU
dc.subject	static magnetic field	ru_RU
dc.subject	phase transformations	ru_RU
dc.subject	ethylammonium nitrate	ru_RU
dc.subject	hydrogen-bonding network	ru_RU
dc.subject	diffusion	ru_RU
dc.title	Self-diffusion in ionic liquids with nitrate anion: Effects of confinement between glass plates and static magnetic field	ru_RU
dc.type	Articles in international journals and collections	ru_RU