KFU. Card publication. Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway

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DIELS-ALDER REACTION RATE IN THE SOLID STATE AND THE EVIDENCE OF THE LOCATION OF MOLECULAR COMPLEXES BETWEEN THE REAGENTS ON THE REACTION PATHWAY

Form of presentation

Articles in international journals and collections

Year of publication

2021

Authors, employees of KFU

Kiselev Vladimir Dmitrievich, author

Klimovickiy Aleksandr Evgenevich, author

Kolesnikova Anastasiya Olegovna, author

Kornilov Dmitriy Anatolevich, author

Other authors

Shulyatev Aleksey Aleksandrovich, Dinikaev Ildar Fanzilevich

Authors, postgraduates KFU

Shulyatev Aleksey Aleksandrovich, postgraduate kfu

Bibliographic description in the original language

Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. ? 2021. ? V.53. ? P.207-212.

Annotation

The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracenetetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway.

Keywords

Diels-Alder reaction, kinetics, molecular complex, solid state

The name of the journal

International Journal of Chemical Kinetics

Publishing house

Wiley

URL

https://doi.org/10.1002/kin.21434

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=249640&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Kiselev Vladimir Dmitrievich	ru_RU
dc.contributor.author	Klimovickiy Aleksandr Evgenevich	ru_RU
dc.contributor.author	Kolesnikova Anastasiya Olegovna	ru_RU
dc.contributor.author	Kornilov Dmitriy Anatolevich	ru_RU
dc.contributor.author	Shulyatev Aleksey Aleksandrovich	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Kiselev V.D., Kolesnikova A.O., Dinikaev I.E., Shulyatiev A.A., Klimovitskii A.E., Kornilov D.A. / Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway // International Journal of Chemical Kinetics. ? 2021. ? V.53. ? P.207-212.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=249640&p_lang=2	ru_RU
dc.description.abstract	International Journal of Chemical Kinetics	ru_RU
dc.description.abstract	The rate of reactions in the solid phase with uniform grinding of crystals of dienes, anthracene, and 9,10-dimethylanthracene, with dienophiles, tetracyanoethylene, N-phenylmaleimide, and 4-phenyl-1,2,4-triazoline-3,5-dione, has been studied. It was shown that, despite the high difference in the reaction rates in solution, the rates of these reactions in the solid phase are much closer. For anthracene-tetracyanoethylene and 9,10-dimethylanthracenetetracyanoethylene pairs, it was concluded that their intermolecular complexes are on the reaction pathway.	ru_RU
dc.language.iso	ru	ru_RU
dc.publisher	Wiley	ru_RU
dc.subject	Diels-Alder reaction	ru_RU
dc.subject	kinetics	ru_RU
dc.subject	molecular complex	ru_RU
dc.subject	solid state	ru_RU
dc.title	Diels-Alder reaction rate in the solid state and the evidence of the location of molecular complexes between the reagents on the reaction pathway	ru_RU
dc.type	Articles in international journals and collections	ru_RU