KFU. Card publication. Oxidation of Heavy Oil Using Oil-Dispersed Transition Metal Acetylacetonate Catalysts for Enhanced Oil Recovery

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FEDERAL UNIVERSITY

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OXIDATION OF HEAVY OIL USING OIL-DISPERSED TRANSITION METAL ACETYLACETONATE CATALYSTS FOR ENHANCED OIL RECOVERY

Form of presentation

Articles in international journals and collections

Year of publication

2021

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Authors, employees of KFU

Baba Pur Gol Afshani Meysam , author

Vagizov Farit Gabdulkhakovich, author

Varfolomeev Mikhail Alekseevich, author

Emelyanov Dmitriy Anatolevich, author

Zinnatullin Almaz Linarovich, author

Mekhrabi Kaladzhakhi Seyedsaid , author

Osin Yuriy Nikolaevich, author

Rodionov Nikolay Olegovich, author

Sadikov Kamil Gamirovich, author

Other authors

Tahay Pooya , author

Bibliographic description in the original language

Oxidation of Heavy Oil Using Oil-Dispersed Transition Metal Acetylacetonate Catalysts for Enhanced Oil Recovery / M. B. Golafshani, M. A. Varfolomeev, S. Mehrabi-Kalajahi, N. O. Rodionov, P. Tahay, A. L. Zinnatullin, D. A. Emelianov, F. G. Vagizov, K. G. Sadikov, Y. N. Osin // Energy & Fuels. - 2021.

Annotation

In this work, several transition metal-based acetylacetonates (Ni, Cu, and Fe) were prepared as oil-dispersed catalysts for heavy oil oxidation. X-ray diffraction (XRD), scanning electron microscopy (SEM), and Mössbauer spectroscopy were used for the characterization of catalysts. The effectivity of catalysts in the oxidation of heavy oil was investigated by a thermogravimetry method coupled with infrared spectroscopy (TG-FTIR) at four different heating rates (4, 6, 8, and 10 ?C/min) and self-designed porous medium thermo-effect cell (PMTEC) techniques. The activation energy calculations using three isoconversional methods, Ozawa–Flynn–Wall (OFW), Kissinger–Akahira–Sunose (KAS), and Friedman, were performed based on thermal analysis data. The results showed that the bidentate ligand acetylacetonate (acac) provided good enough distribution of catalysts in heavy oil because in the presence of Cu(acac)2, Fe(acac)3, and Ni(acac)2, the oxidation temperature decreased in both fuel deposition (FD) and high-temperature oxidation (HTO). The activation energy of FD and HTO districts showed that Cu(acac)2 more efficiently catalyzed the oxidation of heavy oil than Fe(acac)3 and Ni(acac)2. The usage of Cu(acac)2 helped decrease the average activation energy of the in situ combustion process from 177 to 117 kJ/mol, from 187 to 127 kJ/mol, and from 198 to 128 kJ/mol based on OFW, KAS, and Friedman methods, respectively. The in situ transformation of the catalysts in the presence of heavy oil was studied under different isothermal conditions. Based on XRD and SEM data at 400 ?C, Cu(acac)2 and Ni(acac)2 were transformed to CuO and NiO nanoparticles as the active form of catalysts. For Fe(acac)3, it was found that at 400 ?C, it transformed to magnetite (Fe3O4) species; however, at 500 ?C, hematite (α-Fe2O3) and maghemite (γ-Fe2O3) were the most predominant species. The heavy oil oxidation using these low-cost and easy to prepare catalysts could be the best route for improving the efficiency of in situ combustion in field applications.

Keywords

Oxidation reactions, Catalysts, Redox reactions, Lipids, Oxidation, XRD, Mossbauer spectroscopy

The name of the journal

ENERGY & FUELS

URL

https://pubs.acs.org/doi/10.1021/acs.energyfuels.1c03434

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=259799&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Baba Pur Gol Afshani Meysam	ru_RU
dc.contributor.author	Vagizov Farit Gabdulkhakovich	ru_RU
dc.contributor.author	Varfolomeev Mikhail Alekseevich	ru_RU
dc.contributor.author	Emelyanov Dmitriy Anatolevich	ru_RU
dc.contributor.author	Zinnatullin Almaz Linarovich	ru_RU
dc.contributor.author	Mekhrabi Kaladzhakhi Seyedsaid	ru_RU
dc.contributor.author	Osin Yuriy Nikolaevich	ru_RU
dc.contributor.author	Rodionov Nikolay Olegovich	ru_RU
dc.contributor.author	Sadikov Kamil Gamirovich	ru_RU
dc.contributor.author	Tahay Pooya	ru_RU
dc.date.accessioned	2021-01-01T00:00:00Z	ru_RU
dc.date.available	2021-01-01T00:00:00Z	ru_RU
dc.date.issued	2021	ru_RU
dc.identifier.citation	Oxidation of Heavy Oil Using Oil-Dispersed Transition Metal Acetylacetonate Catalysts for Enhanced Oil Recovery / M. B. Golafshani, M. A. Varfolomeev, S. Mehrabi-Kalajahi, N. O. Rodionov, P. Tahay, A. L. Zinnatullin, D. A. Emelianov, F. G. Vagizov, K. G. Sadikov, Y. N. Osin // Energy & Fuels. - 2021.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=259799&p_lang=2	ru_RU
dc.description.abstract	ENERGY & FUELS	ru_RU
dc.description.abstract	In this work, several transition metal-based acetylacetonates (Ni, Cu, and Fe) were prepared as oil-dispersed catalysts for heavy oil oxidation. X-ray diffraction (XRD), scanning electron microscopy (SEM), and Mössbauer spectroscopy were used for the characterization of catalysts. The effectivity of catalysts in the oxidation of heavy oil was investigated by a thermogravimetry method coupled with infrared spectroscopy (TG-FTIR) at four different heating rates (4, 6, 8, and 10 ?C/min) and self-designed porous medium thermo-effect cell (PMTEC) techniques. The activation energy calculations using three isoconversional methods, Ozawa–Flynn–Wall (OFW), Kissinger–Akahira–Sunose (KAS), and Friedman, were performed based on thermal analysis data. The results showed that the bidentate ligand acetylacetonate (acac) provided good enough distribution of catalysts in heavy oil because in the presence of Cu(acac)2, Fe(acac)3, and Ni(acac)2, the oxidation temperature decreased in both fuel deposition (FD) and high-temperature oxidation (HTO). The activation energy of FD and HTO districts showed that Cu(acac)2 more efficiently catalyzed the oxidation of heavy oil than Fe(acac)3 and Ni(acac)2. The usage of Cu(acac)2 helped decrease the average activation energy of the in situ combustion process from 177 to 117 kJ/mol, from 187 to 127 kJ/mol, and from 198 to 128 kJ/mol based on OFW, KAS, and Friedman methods, respectively. The in situ transformation of the catalysts in the presence of heavy oil was studied under different isothermal conditions. Based on XRD and SEM data at 400 ?C, Cu(acac)2 and Ni(acac)2 were transformed to CuO and NiO nanoparticles as the active form of catalysts. For Fe(acac)3, it was found that at 400 ?C, it transformed to magnetite (Fe3O4) species; however, at 500 ?C, hematite (α-Fe2O3) and maghemite (γ-Fe2O3) were the most predominant species. The heavy oil oxidation using these low-cost and easy to prepare catalysts could be the best route for improving the efficiency of in situ combustion in field applications.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Oxidation reactions	ru_RU
dc.subject	Catalysts	ru_RU
dc.subject	Redox reactions	ru_RU
dc.subject	Lipids	ru_RU
dc.subject	Oxidation	ru_RU
dc.subject	XRD	ru_RU
dc.subject	Mossbauer spectroscopy	ru_RU
dc.title	Oxidation of Heavy Oil Using Oil-Dispersed Transition Metal Acetylacetonate Catalysts for Enhanced Oil Recovery	ru_RU
dc.type	Articles in international journals and collections	ru_RU