| Form of presentation | Articles in international journals and collections |
| Year of publication | 2015 |
| Язык | английский |
|
Ziganshina Albina Yulduzovna, author
|
| Bibliographic description in the original language |
V. V. Yanilkin, N. V. Nastapova, G. R. Nasretdinova, R. K. Mukhitova, A. Yu. Ziganshina, I. R. Nizameev, and M. K. Kadirov / Mediated Electrochemical Synthesis of Pd0 Nanoparticles in Solution // Rus. J. Electrochem. – 2015. – 51. – 10. – 951–962. |
| Annotation |
Efficient electrosynthesis of palladium(0) nanoparticles is carried out in solution by mediated electrochemical reduction of a complex dianion [PdCl4]2– in the DMSO/0.1 M Bu4NCl medium. The mediator function was performed by methylviologen and tetraviologen calix[4]resorcines MVCA-C
8+
n with methyl (n = 1), n-pentyl (n = 5), and n-decyl (n = 10) substituents in resorcinol rings at the potentials of redox pairs MV2+/MV?+, MVCA-C
8+
n/MVCA-C
4?+
n. The resulting metal nanoparticles gradually aggregate to yield coarser particles. The smallest size (255 nm) have metal particles obtained in the presence of MVCA-C
8+
5
for the rest mediators, metal particles of the micron size are formed. Sonication results in disintegration of aggregates to nanoparticles. |
| Keywords |
methylviologen, viologen calix[4]resorcine, palladium tetrachloride, mediator, electrochemical reduction, palladium nanoparticle |
| The name of the journal |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY
|
| URL |
https://link.springer.com/article/10.1134/S1023193515100146#citeas |
| Please use this ID to quote from or refer to the card |
https://repository.kpfu.ru/eng/?p_id=262935&p_lang=2 |
Full metadata record  |
| Field DC |
Value |
Language |
| dc.contributor.author |
Ziganshina Albina Yulduzovna |
ru_RU |
| dc.date.accessioned |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.available |
2015-01-01T00:00:00Z |
ru_RU |
| dc.date.issued |
2015 |
ru_RU |
| dc.identifier.citation |
V. V. Yanilkin, N. V. Nastapova, G. R. Nasretdinova, R. K. Mukhitova, A. Yu. Ziganshina, I. R. Nizameev, and M. K. Kadirov / Mediated Electrochemical Synthesis of Pd0 Nanoparticles in Solution // Rus. J. Electrochem. – 2015. – 51. – 10. – 951–962. |
ru_RU |
| dc.identifier.uri |
https://repository.kpfu.ru/eng/?p_id=262935&p_lang=2 |
ru_RU |
| dc.description.abstract |
RUSSIAN JOURNAL OF ELECTROCHEMISTRY |
ru_RU |
| dc.description.abstract |
Efficient electrosynthesis of palladium(0) nanoparticles is carried out in solution by mediated electrochemical reduction of a complex dianion [PdCl4]2– in the DMSO/0.1 M Bu4NCl medium. The mediator function was performed by methylviologen and tetraviologen calix[4]resorcines MVCA-C
8+
n with methyl (n = 1), n-pentyl (n = 5), and n-decyl (n = 10) substituents in resorcinol rings at the potentials of redox pairs MV2+/MV?+, MVCA-C
8+
n/MVCA-C
4?+
n. The resulting metal nanoparticles gradually aggregate to yield coarser particles. The smallest size (255 nm) have metal particles obtained in the presence of MVCA-C
8+
5
for the rest mediators, metal particles of the micron size are formed. Sonication results in disintegration of aggregates to nanoparticles. |
ru_RU |
| dc.language.iso |
ru |
ru_RU |
| dc.subject |
methylviologen |
ru_RU |
| dc.subject |
viologen calix[4]resorcine |
ru_RU |
| dc.subject |
palladium tetrachloride |
ru_RU |
| dc.subject |
mediator |
ru_RU |
| dc.subject |
electrochemical reduction |
ru_RU |
| dc.subject |
palladium nanoparticle |
ru_RU |
| dc.title |
Mediated Electrochemical Synthesis of Pd0 Nanoparticles in Solution |
ru_RU |
| dc.type |
Articles in international journals and collections |
ru_RU |
|
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