KFU. Card publication. Binding of 1,5-bis(p-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane with tetramethylviologen calix[4]resorcin with a methyl radical in the resorcinol ring

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BINDING OF 1,5-BIS(P-SULFONATOPHENYL)-3,7-DIPHENYL-1,5-DIAZA-3,7-DIPHOSPHACYCLOOCTANE WITH TETRAMETHYLVIOLOGEN CALIX[4]RESORCIN WITH A METHYL RADICAL IN THE RESORCINOL RING

Form of presentation

Articles in international journals and collections

Year of publication

2014

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Authors, employees of KFU

Ziganshina Albina Yulduzovna, author

Bibliographic description in the original language

A. Y. Ziganshina, G. R. Nasybullina, V. V. Yanilkin, N. V. Nastapova, D. E. Korshin, Yu. S. Spiridonova, R. R. Kashapov, M. Gruner, W. D. Habicher, A. A. Karasik, A. I. Konovalov / Binding of 1,5-bis(p-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane with tetramethylviologen calix[4]resorcin with a methyl radical in the resorcinol ring // Rus. J. Electrochem. – 2014. – 50. – 142–153.

Annotation

The binding of the amphiphilic 1,5-bis(para-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane dianion (APCO2−) with the octacation of the amphiphilic tetramethylviologen calix[4]resorcin having a methyl radical in the resorcinol ring (MVCA-C8+ 1) in 30% aqueous DMSO in a 0.1M NaCl supporting solution was studied by various methods. The dianion was bound at the upper rim of calixresorcin due to the donor-acceptor interactions between the viologen acceptor units and the nitrogen- and phosphorus-centered electron-donor fragments of APCO2− and at the lower rim due to hydrophobic interactions. The composition of the complex depended on the MVCA-C8+1: APCO2− ratio. The complexes aggregated, forming insoluble precipitates. MVCA-C 8+1-APCO2− is a system with reversibly electro-switchable aggregation. The starting MVCA- 8+1 octacation partially bound APCO2−, a certain quantity of both substrates remaining in a free state in solution. The MVCA-C 4+?1 tetraradical tetracation formed as a result of the reduction of MVCA-C 8+1 completely bound APCO2− due to hydrophobic interactions when the MVCA-C 8+1: APCO2− ratio was 1: 3. The reversible oxidation of MVCA-C 4+?1 to the starting MVCA-C 8+1 octacation brought the system back to its starting state

Keywords

calix[4]resorcin, methylviologen, amphiphilic cyclic diphosphine, complex, aggregation, electroswitchable aggregation

The name of the journal

RUSSIAN JOURNAL OF ELECTROCHEMISTRY

URL

https://link.springer.com/article/10.1134/S1023193513040150#citeas

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=262941&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziganshina Albina Yulduzovna	ru_RU
dc.date.accessioned	2014-01-01T00:00:00Z	ru_RU
dc.date.available	2014-01-01T00:00:00Z	ru_RU
dc.date.issued	2014	ru_RU
dc.identifier.citation	A. Y. Ziganshina, G. R. Nasybullina, V. V. Yanilkin, N. V. Nastapova, D. E. Korshin, Yu. S. Spiridonova, R. R. Kashapov, M. Gruner, W. D. Habicher, A. A. Karasik, A. I. Konovalov / Binding of 1,5-bis(p-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane with tetramethylviologen calix[4]resorcin with a methyl radical in the resorcinol ring // Rus. J. Electrochem. – 2014. – 50. – 142–153.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=262941&p_lang=2	ru_RU
dc.description.abstract	RUSSIAN JOURNAL OF ELECTROCHEMISTRY	ru_RU
dc.description.abstract	The binding of the amphiphilic 1,5-bis(para-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane dianion (APCO2−) with the octacation of the amphiphilic tetramethylviologen calix[4]resorcin having a methyl radical in the resorcinol ring (MVCA-C8+ 1) in 30% aqueous DMSO in a 0.1M NaCl supporting solution was studied by various methods. The dianion was bound at the upper rim of calixresorcin due to the donor-acceptor interactions between the viologen acceptor units and the nitrogen- and phosphorus-centered electron-donor fragments of APCO2− and at the lower rim due to hydrophobic interactions. The composition of the complex depended on the MVCA-C8+1: APCO2− ratio. The complexes aggregated, forming insoluble precipitates. MVCA-C 8+1-APCO2− is a system with reversibly electro-switchable aggregation. The starting MVCA- 8+1 octacation partially bound APCO2−, a certain quantity of both substrates remaining in a free state in solution. The MVCA-C 4+?1 tetraradical tetracation formed as a result of the reduction of MVCA-C 8+1 completely bound APCO2− due to hydrophobic interactions when the MVCA-C 8+1: APCO2− ratio was 1: 3. The reversible oxidation of MVCA-C 4+?1 to the starting MVCA-C 8+1 octacation brought the system back to its starting state	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	calix[4]resorcin	ru_RU
dc.subject	methylviologen	ru_RU
dc.subject	amphiphilic cyclic diphosphine	ru_RU
dc.subject	complex	ru_RU
dc.subject	aggregation	ru_RU
dc.subject	electroswitchable aggregation	ru_RU
dc.title	Binding of 1,5-bis(p-sulfonatophenyl)-3,7-diphenyl-1,5-diaza-3,7-diphosphacyclooctane with tetramethylviologen calix[4]resorcin with a methyl radical in the resorcinol ring	ru_RU
dc.type	Articles in international journals and collections	ru_RU