Kazan (Volga region) Federal University, KFU
KAZAN
FEDERAL UNIVERSITY
 
ELECTROCHEMICAL CONTROL OF ASSOCIATION AND DEPOSITION OF TETRAVIOLOGEN CALIX[4]RESORCIN
Form of presentationArticles in international journals and collections
Year of publication2014
Языканглийский
  • Ziganshina Albina Yulduzovna, author
  • Bibliographic description in the original language G. R. Nasybullina, V. V. Yanilkin, A. Y. Ziganshina, V. I. Morozov, E. D. Sultanova, D. E. Korshin, V. A. Milyukov, R. P.Shekurov, A. I. Konovalov / Electrochemical Control of Association and Deposition of Tetraviologen Calix[4]resorcin // Rus. J. Electrochem. – 2014. – 50. – 756–772.
    Annotation The association and deposition of tetraviologen calix[4]resorcin MVCA-C 8+ 5 can be controlled using the electrochemical reduction-reoxidation cycle of viologen units. The monomeric MVCA-C 8+ 5 was converted into the highly molecular (MVCA-C 4+? 5 ) n associate (π-polymer) by reducing it to the MVCA-C 4+? 5 tetra(radical cation) and completely returns to the starting monomeric state by reverse oxidation. The reduction to the neutral state MVCA-C 0 5 allowed calixresorcin to pass from solution to precipitate and the reverse oxidation led to its returning in solution.
    Keywords calix[4]resorcin, methylviologen, association, precipitation, electrochemical control
    The name of the journal RUSSIAN JOURNAL OF ELECTROCHEMISTRY
    URL https://link.springer.com/article/10.1134/S1023193514080096#citeas
    Please use this ID to quote from or refer to the card https://repository.kpfu.ru/eng/?p_id=262943&p_lang=2

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