KFU. Card publication. Oil dispersed nickel-based catalyst for catalytic upgrading of heavy oil using supercritical water

KAZAN
FEDERAL UNIVERSITY

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- 中文
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OIL DISPERSED NICKEL-BASED CATALYST FOR CATALYTIC UPGRADING OF HEAVY OIL USING SUPERCRITICAL WATER

Form of presentation

Articles in international journals and collections

Year of publication

2022

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Authors, employees of KFU

Al-Muntaser Amin Akhmed Mokhammed , author

Varfolomeev Mikhail Alekseevich, author

Galeev Ranel Ilnurovich, author

Davletshin Rustam Rifkhatovich, author

Dzhimasbe Richard , author

Zinnatullin Almaz Linarovich, author

Kvofie Maykl , author

Klochkov Vladimir Vasilevich, author

Rakhmatullin Ilfat Zufarovich, author

Suveyd Munir Abdo Mokhammed , author

Feoktistov Dmitriy Aleksandrovich, author

Yuan Chengdong , author

Other authors

Prochukhan Konstantin , author

Bibliographic description in the original language

Djimasbe R., Oil dispersed nickel-based catalyst for catalytic upgrading of heavy oil using supercritical water / Djimasbe R., Varfolomeev M.A., Al-Muntaser A.A., Yuan C., Feoktistov D.A., Suwaid M.A., Kirgizov A.J., Davletshin R.R., Zinnatullin A.L., Fatou S.D., Galeev R.I., Rakhmatullin I.Z., Kwofie M., Klochkov V.V., Prochukhan K.Y. // Fuel. - 2022. - Vol. 313. - P. 1122702.

Annotation

Upgrading of heavy oil using supercritical water (SCW) has attracted a lot of attention recently due to the unique properties of SCW to act as hydrogen donor source and good solvent for organic matters. In this study, nickel-based oil-dispersed catalyst was used to intensify heavy oil upgrading in SCW. Its catalytic activity on upgrading performance and its influence on environment (from the point of the contamination of wastewater obtained after SCW treatments) were assessed. The result revealed that Ni-based catalysts increased the yield of upgraded oil to 89.73% from 81.99%, while reduced the yield of gases and coke to 8% and 2.27% from 14.92% and 3.09%, respectively. With catalysts, the heavy oil (API gravity 14? and viscosity 2073 mPa?s) was upgraded to light oil (API gravity 26.10? and viscosity 19.8 mPa?s) with a higher H/C ratio and lower content of S, N, and metals. Moreover, an obvious change in the composition and structure of upgraded oil was found, including a significant decrease in resins and asphaltenes content with an increase in saturate content; an increase in C7-C20 alkanes content with a decrease in C21-C30 alkanes; a significant conversion of poly-aromatics into di-aromatics; a decrease in the mean chain length (MCL), aromaticity factor (FCA), aromatic (Car carbons), and secondary + quaternary group (Csq) with an increase in primary group (−CH3, Cp) and tertiary group (Ct) in the structure of resins and asphaltenes, etc., proved by SARA analysis, elemental analysis, FTIR spectra, GC, GC–MS, and 13C NMR spectroscopy. In addition, we found that waste water was less contaminated by oil and paramagnetic ions, confirmed by visual observation, scanning optical microscope, and low-field NMR measurements. All these significant improvements in upgrading performance resulted from the in-situ transformation of oil-dispersed Ni-based catalysts into Ni3S2; Ni9S8; NiS; NiO; and Ni[OH]2 in oil environment. These in-situ formed active phases of Ni acted as electro-catalysts for water splitting reactions to promote the participation of water in upgrading process as hydrogen source, and simultaneously accelerated isomerization, hydrogenation, alkylation, and opening ring reactions, which consequently results in a higher yield of upgraded oil with a better quality as well as less contaminated waste water.

Keywords

Catalytic upgrading, Heavy oil, Nickel-based catalyst, Oil-dispersed catalyst, Supercritical water, Wastewater

The name of the journal

Fuel

URL

https://www.sciencedirect.com/science/article/pii/S0016236121025679?via%3Dihub

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=263971&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Al-Muntaser Amin Akhmed Mokhammed	ru_RU
dc.contributor.author	Varfolomeev Mikhail Alekseevich	ru_RU
dc.contributor.author	Galeev Ranel Ilnurovich	ru_RU
dc.contributor.author	Davletshin Rustam Rifkhatovich	ru_RU
dc.contributor.author	Dzhimasbe Richard	ru_RU
dc.contributor.author	Zinnatullin Almaz Linarovich	ru_RU
dc.contributor.author	Kvofie Maykl	ru_RU
dc.contributor.author	Klochkov Vladimir Vasilevich	ru_RU
dc.contributor.author	Rakhmatullin Ilfat Zufarovich	ru_RU
dc.contributor.author	Suveyd Munir Abdo Mokhammed	ru_RU
dc.contributor.author	Feoktistov Dmitriy Aleksandrovich	ru_RU
dc.contributor.author	Yuan Chengdong	ru_RU
dc.contributor.author	Prochukhan Konstantin	ru_RU
dc.date.accessioned	2022-01-01T00:00:00Z	ru_RU
dc.date.available	2022-01-01T00:00:00Z	ru_RU
dc.date.issued	2022	ru_RU
dc.identifier.citation	Djimasbe R., Oil dispersed nickel-based catalyst for catalytic upgrading of heavy oil using supercritical water / Djimasbe R., Varfolomeev M.A., Al-Muntaser A.A., Yuan C., Feoktistov D.A., Suwaid M.A., Kirgizov A.J., Davletshin R.R., Zinnatullin A.L., Fatou S.D., Galeev R.I., Rakhmatullin I.Z., Kwofie M., Klochkov V.V., Prochukhan K.Y. // Fuel. - 2022. - Vol. 313. - P. 1122702.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=263971&p_lang=2	ru_RU
dc.description.abstract	Fuel	ru_RU
dc.description.abstract	Upgrading of heavy oil using supercritical water (SCW) has attracted a lot of attention recently due to the unique properties of SCW to act as hydrogen donor source and good solvent for organic matters. In this study, nickel-based oil-dispersed catalyst was used to intensify heavy oil upgrading in SCW. Its catalytic activity on upgrading performance and its influence on environment (from the point of the contamination of wastewater obtained after SCW treatments) were assessed. The result revealed that Ni-based catalysts increased the yield of upgraded oil to 89.73% from 81.99%, while reduced the yield of gases and coke to 8% and 2.27% from 14.92% and 3.09%, respectively. With catalysts, the heavy oil (API gravity 14? and viscosity 2073 mPa?s) was upgraded to light oil (API gravity 26.10? and viscosity 19.8 mPa?s) with a higher H/C ratio and lower content of S, N, and metals. Moreover, an obvious change in the composition and structure of upgraded oil was found, including a significant decrease in resins and asphaltenes content with an increase in saturate content; an increase in C7-C20 alkanes content with a decrease in C21-C30 alkanes; a significant conversion of poly-aromatics into di-aromatics; a decrease in the mean chain length (MCL), aromaticity factor (FCA), aromatic (Car carbons), and secondary + quaternary group (Csq) with an increase in primary group (−CH3, Cp) and tertiary group (Ct) in the structure of resins and asphaltenes, etc., proved by SARA analysis, elemental analysis, FTIR spectra, GC, GC–MS, and 13C NMR spectroscopy. In addition, we found that waste water was less contaminated by oil and paramagnetic ions, confirmed by visual observation, scanning optical microscope, and low-field NMR measurements. All these significant improvements in upgrading performance resulted from the in-situ transformation of oil-dispersed Ni-based catalysts into Ni3S2; Ni9S8; NiS; NiO; and Ni[OH]2 in oil environment. These in-situ formed active phases of Ni acted as electro-catalysts for water splitting reactions to promote the participation of water in upgrading process as hydrogen source, and simultaneously accelerated isomerization, hydrogenation, alkylation, and opening ring reactions, which consequently results in a higher yield of upgraded oil with a better quality as well as less contaminated waste water.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Catalytic upgrading	ru_RU
dc.subject	Heavy oil	ru_RU
dc.subject	Nickel-based catalyst	ru_RU
dc.subject	Oil-dispersed catalyst	ru_RU
dc.subject	Supercritical water	ru_RU
dc.subject	Wastewater	ru_RU
dc.title	Oil dispersed nickel-based catalyst for catalytic upgrading of heavy oil using supercritical water	ru_RU
dc.type	Articles in international journals and collections	ru_RU