KFU. Card publication. Growth and characterization of optical and thermal properties of LiGdF4 single crystal

KAZAN
FEDERAL UNIVERSITY

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- 中文
- ES

GROWTH AND CHARACTERIZATION OF OPTICAL AND THERMAL PROPERTIES OF LIGDF4 SINGLE CRYSTAL

Form of presentation

Articles in international journals and collections

Year of publication

2023

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Authors, employees of KFU

Klimovickiy Aleksandr Evgenevich, author

Korableva Stella Leonidovna, author

Morozov Oleg Aleksandrovich, author

Pudovkin Maksim Sergeevich, author

Semashko Vadim Vladimirovich, author

Bibliographic description in the original language

Morozov, O. A., Korableva, S. L., Nurtdinova, L. A., Kyashkin, V. M., Popov, P. A., Klimovitskii, A. E., Pudovkin M.S., Semashko, V. V. (2023). Growth and characterization of optical and thermal properties of LiGdF4 single crystal. Optical Materials, 137, 113490.

Annotation

The opportunity of growing of several centimeters in length LiGdF4 single crystals by Bridgman–Stockbarger technique was demonstrated and the optically perfect LiGdF4 single crystals with 8 mm and 55 mm in length were grown. The phase composition, thermal conductivity, basic optical and spectral-kinetic properties of LiGdF4 single crystals were studied for the first time. For LiGdF4 crystal, the resulting linear thermal expansion coefficients α is 11% larger, than for both LiYF4 and LiYbF4 crystals. The obtained thermal conductivity dependence k(T) is more pronounced compared to LiLuF4 and LiYF4. The absorption spectrum of the LiGdF4 crystal shows absorption bands corresponding to the 8S7/2 – (6Dj, 6Ij, and 6Pj) transitions of Gd3+ ions. The measured room temperature lifetime of 6Pj multiplet of Gd3+ ions was equal to 4.25 ? 0.05 ms. The values of the temperature gradient of the LiGdF4 refractive index do not strongly depend on the wavelength.

Keywords

Keywords: LiGdF4 Thermal conductivity FTIR absorption spectroscopy Optical constants

The name of the journal

Optical Materials

URL

https://www.sciencedirect.com/science/article/pii/S0925346723000617

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=275957&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Klimovickiy Aleksandr Evgenevich	ru_RU
dc.contributor.author	Korableva Stella Leonidovna	ru_RU
dc.contributor.author	Morozov Oleg Aleksandrovich	ru_RU
dc.contributor.author	Pudovkin Maksim Sergeevich	ru_RU
dc.contributor.author	Semashko Vadim Vladimirovich	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Morozov, O. A., Korableva, S. L., Nurtdinova, L. A., Kyashkin, V. M., Popov, P. A., Klimovitskii, A. E., Pudovkin M.S., Semashko, V. V. (2023). Growth and characterization of optical and thermal properties of LiGdF4 single crystal. Optical Materials, 137, 113490.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=275957&p_lang=2	ru_RU
dc.description.abstract	Optical Materials	ru_RU
dc.description.abstract	The opportunity of growing of several centimeters in length LiGdF4 single crystals by Bridgman–Stockbarger technique was demonstrated and the optically perfect LiGdF4 single crystals with 8 mm and 55 mm in length were grown. The phase composition, thermal conductivity, basic optical and spectral-kinetic properties of LiGdF4 single crystals were studied for the first time. For LiGdF4 crystal, the resulting linear thermal expansion coefficients α is 11% larger, than for both LiYF4 and LiYbF4 crystals. The obtained thermal conductivity dependence k(T) is more pronounced compared to LiLuF4 and LiYF4. The absorption spectrum of the LiGdF4 crystal shows absorption bands corresponding to the 8S7/2 – (6Dj, 6Ij, and 6Pj) transitions of Gd3+ ions. The measured room temperature lifetime of 6Pj multiplet of Gd3+ ions was equal to 4.25 ? 0.05 ms. The values of the temperature gradient of the LiGdF4 refractive index do not strongly depend on the wavelength.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject		ru_RU
dc.title	Growth and characterization of optical and thermal properties of LiGdF4 single crystal	ru_RU
dc.type	Articles in international journals and collections	ru_RU