KFU. Card publication. Selective Voltammetric Sensor for the Simultaneous Quantification of Tartrazine and Brilliant Blue FCF

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FEDERAL UNIVERSITY

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SELECTIVE VOLTAMMETRIC SENSOR FOR THE SIMULTANEOUS QUANTIFICATION OF TARTRAZINE AND BRILLIANT BLUE FCF

Form of presentation

Articles in international journals and collections

Year of publication

2023

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Authors, employees of KFU

Davletshin Rustam Rifkhatovich, author

Ziyatdinova Guzel Kamilevna, author

Authors, postgraduates KFU

Gimadutdinova Liliya Timurovna, postgraduate kfu

Bibliographic description in the original language

Gimadutdinova, L. Selective voltammetric sensor for the simultaneous quantification of tartrazine and brilliant blue FCF / L. Gimadutdinova, G. Ziyatdinova, R. Davletshin // Sensors. - 2023. - V. 23. - � 3. - Article 1094. - 19 p.

Annotation

Tartrazine and brilliant blue FCF are synthetic dyes used in the food, cosmetic and pharmaceutical industries. The individual and/or simultaneous control of their concentrations is required due to dose-dependent negative health effects. Therefore, the paper presents experimental results related to the development of a sensing platform for the electrochemical detection of tartrazine and brilliant blue FCF based on a glassy carbon electrode (GCE) modified with MnO2 nanorods, using anodic differential pulse voltammetry. Homogeneous and stable suspensions of MnO2 nanorods have been obtained involving cetylpyridinium bromide solution as a cationic surfactant. The MnO2 nanorods-modified electrode showed a 7.9-fold increase in the electroactive surface area and a 72-fold decrease in the electron transfer resistance. The developed sensor allowed the simultaneous quantification of dyes for two linear domains: in the ranges of 0.10?2.5 and 2.5?15 μM for tartrazine and 0.25?2.5 and 2.5?15 μM for brilliant blue FCF with detection limits of 43 and 41 nM, respectively. High selectivity of the sensor response in the presence of typical interference agents (inorganic ions, saccharides, ascorbic and sorbic acids), other food dyes (riboflavin, indigo carmine, and sunset yellow), and vanillin has been achieved. The sensor has been tested by analyzing soft and isotonic sports drinks and the determined concentrations were close to those obtained involving the chromatography technique.

Keywords

Voltammetric sensors, chemically modified electrodes, metal oxide nanomaterials, synthetic dyes, beverages, food analysis

The name of the journal

Sensors

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=278343&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Davletshin Rustam Rifkhatovich	ru_RU
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Gimadutdinova Liliya Timurovna	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Gimadutdinova, L. Selective voltammetric sensor for the simultaneous quantification of tartrazine and brilliant blue FCF / L. Gimadutdinova, G. Ziyatdinova, R. Davletshin // Sensors. - 2023. - V. 23. - � 3. - Article 1094. - 19 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=278343&p_lang=2	ru_RU
dc.description.abstract	Sensors	ru_RU
dc.description.abstract	Tartrazine and brilliant blue FCF are synthetic dyes used in the food, cosmetic and pharmaceutical industries. The individual and/or simultaneous control of their concentrations is required due to dose-dependent negative health effects. Therefore, the paper presents experimental results related to the development of a sensing platform for the electrochemical detection of tartrazine and brilliant blue FCF based on a glassy carbon electrode (GCE) modified with MnO2 nanorods, using anodic differential pulse voltammetry. Homogeneous and stable suspensions of MnO2 nanorods have been obtained involving cetylpyridinium bromide solution as a cationic surfactant. The MnO2 nanorods-modified electrode showed a 7.9-fold increase in the electroactive surface area and a 72-fold decrease in the electron transfer resistance. The developed sensor allowed the simultaneous quantification of dyes for two linear domains: in the ranges of 0.10?2.5 and 2.5?15 μM for tartrazine and 0.25?2.5 and 2.5?15 μM for brilliant blue FCF with detection limits of 43 and 41 nM, respectively. High selectivity of the sensor response in the presence of typical interference agents (inorganic ions, saccharides, ascorbic and sorbic acids), other food dyes (riboflavin, indigo carmine, and sunset yellow), and vanillin has been achieved. The sensor has been tested by analyzing soft and isotonic sports drinks and the determined concentrations were close to those obtained involving the chromatography technique.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Voltammetric sensors	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	metal oxide nanomaterials	ru_RU
dc.subject	synthetic dyes	ru_RU
dc.subject	beverages	ru_RU
dc.subject	food analysis	ru_RU
dc.title	Selective Voltammetric Sensor for the Simultaneous Quantification of Tartrazine and Brilliant Blue FCF	ru_RU
dc.type	Articles in international journals and collections	ru_RU