KFU. Card publication. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

LAYER-BY-LAYER COMBINATION OF MWCNTS AND POLY(FERULIC ACID) AS ELECTROCHEMICAL PLATFORM FOR HESPERIDIN QUANTIFICATION

Form of presentation

Articles in international journals and collections

Year of publication

2023

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Authors, employees of KFU

Ziyatdinova Guzel Kamilevna, author

Other authors

Mukharlyamova Aysylu , author

Ficev Igor , author

Authors, postgraduates KFU

Yakupova Elvira Nailevna, postgraduate kfu

Bibliographic description in the original language

Yakupova, E. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification / E. Yakupova, A. Mukharlyamova, I. Fitsev, G. Ziyatdinova // Biosensors. – 2023. – V. 13. – � 5.- Article 500. – 19 p.

Annotation

The electrochemical polymerization of suitable monomers is a powerful way to create voltammetric sensors with improved responses to a target analyte. Nonconductive polymers based on phenolic acids were successfully combined with carbon nanomaterials to obtain sufficient conductivity and high surface area of the electrode. Glassy carbon electrodes (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and electropolymerized ferulic acid (FA) were developed for the sensitive quantification of hesperidin. The optimized conditions of FA electropolymerization in basic medium (15 cycles from −0.2 to 1.0 V at 100 mV s−1 in 250 ?mol L−1 monomer solution in 0.1 mol L−1 NaOH) were found using the voltammetric response of hesperidin. The polymer-modified electrode exhibited a high electroactive surface area (1.14 ? 0.05 cm2 vs. 0.75 ? 0.03 and 0.089 ? 0.003 cm2 for MWCNTs/GCE and bare GCE, respectively) and decreased in the charge transfer resistance (21.4 ? 0.9 kΩ vs. 72 ? 3 kΩ for bare GCE). Under optimized conditions, hesperidin linear dynamic ranges of 0.025–1.0 and 1.0–10 ?mol L−1 with a detection limit of 7.0 nmol L−1 were achieved, which were the best ones among those reported to date. The developed electrode was tested on orange juice and compared with chromatography.

Keywords

Voltammetric sensors, chemically modified electrodes, carbon nanomaterials, electropolymerization, phenolic acids, flavanones, hesperidin

The name of the journal

Biosensors

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85160299774&doi=10.3390%2fbios13050500&partnerID=40&md5=faced03c873b2d1bad905acc7906ada0

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=282385&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Mukharlyamova Aysylu	ru_RU
dc.contributor.author	Ficev Igor	ru_RU
dc.contributor.author	Yakupova Elvira Nailevna	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Yakupova, E. Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification / E. Yakupova, A. Mukharlyamova, I. Fitsev, G. Ziyatdinova // Biosensors. – 2023. – V. 13. – � 5.- Article 500. – 19 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=282385&p_lang=2	ru_RU
dc.description.abstract	Biosensors	ru_RU
dc.description.abstract	The electrochemical polymerization of suitable monomers is a powerful way to create voltammetric sensors with improved responses to a target analyte. Nonconductive polymers based on phenolic acids were successfully combined with carbon nanomaterials to obtain sufficient conductivity and high surface area of the electrode. Glassy carbon electrodes (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and electropolymerized ferulic acid (FA) were developed for the sensitive quantification of hesperidin. The optimized conditions of FA electropolymerization in basic medium (15 cycles from −0.2 to 1.0 V at 100 mV s−1 in 250 ?mol L−1 monomer solution in 0.1 mol L−1 NaOH) were found using the voltammetric response of hesperidin. The polymer-modified electrode exhibited a high electroactive surface area (1.14 ? 0.05 cm2 vs. 0.75 ? 0.03 and 0.089 ? 0.003 cm2 for MWCNTs/GCE and bare GCE, respectively) and decreased in the charge transfer resistance (21.4 ? 0.9 kΩ vs. 72 ? 3 kΩ for bare GCE). Under optimized conditions, hesperidin linear dynamic ranges of 0.025–1.0 and 1.0–10 ?mol L−1 with a detection limit of 7.0 nmol L−1 were achieved, which were the best ones among those reported to date. The developed electrode was tested on orange juice and compared with chromatography.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Voltammetric sensors	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	carbon nanomaterials	ru_RU
dc.subject	electropolymerization	ru_RU
dc.subject	phenolic acids	ru_RU
dc.subject	flavanones	ru_RU
dc.subject	hesperidin	ru_RU
dc.title	Layer-by-layer combination of MWCNTs and poly(ferulic acid) as electrochemical platform for hesperidin quantification	ru_RU
dc.type	Articles in international journals and collections	ru_RU