KFU. Card publication. Highly Sensitive Determination of Hesperidin Using Electrode Modified with Poly(Ferulic Acid)

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

HIGHLY SENSITIVE DETERMINATION OF HESPERIDIN USING ELECTRODE MODIFIED WITH POLY(FERULIC ACID)

Form of presentation

Articles in international journals and collections

Year of publication

2023

��

��

Authors, employees of KFU

Ziyatdinova Guzel Kamilevna, author

Authors, postgraduates KFU

Yakupova Elvira Nailevna, postgraduate kfu

Bibliographic description in the original language

Yakupova, E. Highly sensitive determination of hesperidin using electrode modified with poly(ferulic acid) / E. Yakupova, G. Ziyatdinova // Eng. Proc. – 2023. – V. 31. – � 1. – Article 1. – 5 p.

Annotation

Hesperidin is a major phenolic antioxidant in orange fruits and is responsible for their positive health effect. It is used as part of the therapy for blood vessel conditions. Methods for hesperidin quantification are of practical interest. Recently, several voltammetric approaches have been developed for hesperidin quantification. Nevertheless, the analytical characteristics could be improved. To solve this problem, a glassy carbon electrode (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and poly(ferulic acid) has been developed. Polymeric coverage has been obtained electrochemically under potentiodynamic conditions. Their optimization based on the hesperidin voltammetric response has been performed. The poly(ferulic acid) layer has to be obtained from 250 ?M monomer solution in 0.1 M NaOH by fifteen potential scans from −0.2 to 1.0 V with the scan rate of 100 mV s−1. Hesperidin oxidation currents are 2.8-fold increased at the polymer-modified electrode vs. carbon nanotube-based electrode at the same oxidation potential. Differential pulse voltammetry in phosphate buffer pH 5.5 has been used for the quantification of hesperidin. Linear dynamic ranges of 0.025–1.0 ?M and 1.0–10 ?M have been achieved with the limits of detection and quantification of 7.0 and 23.4 nM, respectively. The analytical characteristics obtained are the best ones reported to date.

Keywords

Voltammetry, modified electrodes, electropolymerization, phenolic acids, flavanones

The name of the journal

Engineering Proceedings

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85163595365&doi=10.3390%2fASEC2022-13786&partnerID=40&md5=223550490bfe1bae2d9ac5aaade9db69

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=286667&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Yakupova Elvira Nailevna	ru_RU
dc.date.accessioned	2023-01-01T00:00:00Z	ru_RU
dc.date.available	2023-01-01T00:00:00Z	ru_RU
dc.date.issued	2023	ru_RU
dc.identifier.citation	Yakupova, E. Highly sensitive determination of hesperidin using electrode modified with poly(ferulic acid) / E. Yakupova, G. Ziyatdinova // Eng. Proc. – 2023. – V. 31. – � 1. – Article 1. – 5 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=286667&p_lang=2	ru_RU
dc.description.abstract	Engineering Proceedings	ru_RU
dc.description.abstract	Hesperidin is a major phenolic antioxidant in orange fruits and is responsible for their positive health effect. It is used as part of the therapy for blood vessel conditions. Methods for hesperidin quantification are of practical interest. Recently, several voltammetric approaches have been developed for hesperidin quantification. Nevertheless, the analytical characteristics could be improved. To solve this problem, a glassy carbon electrode (GCE) modified with multi-walled carbon nanotubes (MWCNTs) and poly(ferulic acid) has been developed. Polymeric coverage has been obtained electrochemically under potentiodynamic conditions. Their optimization based on the hesperidin voltammetric response has been performed. The poly(ferulic acid) layer has to be obtained from 250 ?M monomer solution in 0.1 M NaOH by fifteen potential scans from −0.2 to 1.0 V with the scan rate of 100 mV s−1. Hesperidin oxidation currents are 2.8-fold increased at the polymer-modified electrode vs. carbon nanotube-based electrode at the same oxidation potential. Differential pulse voltammetry in phosphate buffer pH 5.5 has been used for the quantification of hesperidin. Linear dynamic ranges of 0.025–1.0 ?M and 1.0–10 ?M have been achieved with the limits of detection and quantification of 7.0 and 23.4 nM, respectively. The analytical characteristics obtained are the best ones reported to date.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Voltammetry	ru_RU
dc.subject	modified electrodes	ru_RU
dc.subject	electropolymerization	ru_RU
dc.subject	phenolic acids	ru_RU
dc.subject	flavanones	ru_RU
dc.title	Highly Sensitive Determination of Hesperidin Using Electrode Modified with Poly(Ferulic Acid)	ru_RU
dc.type	Articles in international journals and collections	ru_RU