KFU. Card publication. Voltammetric Sensor Based on the Combination of Tin and Cerium Dioxide Nanoparticles with Surfactants for Quantification of Sunset Yellow FCF

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VOLTAMMETRIC SENSOR BASED ON THE COMBINATION OF TIN AND CERIUM DIOXIDE NANOPARTICLES WITH SURFACTANTS FOR QUANTIFICATION OF SUNSET YELLOW FCF

Form of presentation

Articles in international journals and collections

Year of publication

2024

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Authors, employees of KFU

Davletshin Rustam Rifkhatovich, author

Ziyatdinova Guzel Kamilevna, author

Authors, postgraduates KFU

Gimadutdinova Liliya Timurovna, postgraduate kfu

Bibliographic description in the original language

Gimadutdinova, L. Voltammetric sensor based on the combination of tin and cerium dioxide nanoparticles with surfactants for quantification of Sunset Yellow FCF / L. Gimadutdinova, G. Ziyatdinova, R. Davletshin // Sensors. - 2024. - V. 24. - � 3. - Art. 930. - 17 p.

Annotation

Sunset Yellow FCF (SY FCF) is one of the widely used synthetic azo dyes in the food industry whose content has to be controlled for safety reasons. Electrochemical sensors are a promising tool for this type of task. A voltammetric sensor based on a combination of tin and cerium dioxide nanoparticles (SnO2?CeO2 NPs) with surfactants has been developed for SY FCF determination. The synergetic effect of both types of NPs has been confirmed. Surfactants of various natures (sodium lauryl sulfate (SLS), Brij? 35, and hexadecylpyridinium bromide (HDPB)) have been tested as dispersive media. The best effects, i.e., the highest oxidation currents of SY FCF, have been observed in the case of HDPB. The sensor demonstrates a 4.5-fold-higher electroactive surface area and a 38-fold-higher electron transfer rate compared to the bare glassy carbon electrode (GCE). The electrooxidation of SY FCF is an irreversible, two-electron, diffusion-driven process involving proton transfer. In differential pulse mode in Britton?Robinson buffer (BRB) pH 2.0, the sensor gives a linear response to SY FCF from 0.010 to 1.0 μM and from 1.0 to 100 μM with an 8.0 nM detection limit. The absence of an interferent effect from other typical food components and colorants has been shown. The sensor has been tested on soft drinks and validated with the standard chromatographic method.

Keywords

Electrochemical sensors, chemically modified electrodes, metal oxide nanoparticles, surfactants, food colorants, azo dyes

The name of the journal

Sensors

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-85184665066&doi=10.3390%2fs24030930&partnerID=40&md5=2db3948b0ea1748dbfe4f314fca70d93

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=296136&p_lang=2

Full metadata record

Field DC	Value	Language
dc.contributor.author	Davletshin Rustam Rifkhatovich	ru_RU
dc.contributor.author	Ziyatdinova Guzel Kamilevna	ru_RU
dc.contributor.author	Gimadutdinova Liliya Timurovna	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Gimadutdinova, L. Voltammetric sensor based on the combination of tin and cerium dioxide nanoparticles with surfactants for quantification of Sunset Yellow FCF / L. Gimadutdinova, G. Ziyatdinova, R. Davletshin // Sensors. - 2024. - V. 24. - � 3. - Art. 930. - 17 p.	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=296136&p_lang=2	ru_RU
dc.description.abstract	Sensors	ru_RU
dc.description.abstract	Sunset Yellow FCF (SY FCF) is one of the widely used synthetic azo dyes in the food industry whose content has to be controlled for safety reasons. Electrochemical sensors are a promising tool for this type of task. A voltammetric sensor based on a combination of tin and cerium dioxide nanoparticles (SnO2?CeO2 NPs) with surfactants has been developed for SY FCF determination. The synergetic effect of both types of NPs has been confirmed. Surfactants of various natures (sodium lauryl sulfate (SLS), Brij? 35, and hexadecylpyridinium bromide (HDPB)) have been tested as dispersive media. The best effects, i.e., the highest oxidation currents of SY FCF, have been observed in the case of HDPB. The sensor demonstrates a 4.5-fold-higher electroactive surface area and a 38-fold-higher electron transfer rate compared to the bare glassy carbon electrode (GCE). The electrooxidation of SY FCF is an irreversible, two-electron, diffusion-driven process involving proton transfer. In differential pulse mode in Britton?Robinson buffer (BRB) pH 2.0, the sensor gives a linear response to SY FCF from 0.010 to 1.0 μM and from 1.0 to 100 μM with an 8.0 nM detection limit. The absence of an interferent effect from other typical food components and colorants has been shown. The sensor has been tested on soft drinks and validated with the standard chromatographic method.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	Electrochemical sensors	ru_RU
dc.subject	chemically modified electrodes	ru_RU
dc.subject	metal oxide nanoparticles	ru_RU
dc.subject	surfactants	ru_RU
dc.subject	food colorants	ru_RU
dc.subject	azo dyes	ru_RU
dc.title	Voltammetric Sensor Based on the Combination of Tin and Cerium Dioxide Nanoparticles with Surfactants for Quantification of Sunset Yellow FCF	ru_RU
dc.type	Articles in international journals and collections	ru_RU