KFU. Card publication. Journal of Structural Chemistry

KAZAN
FEDERAL UNIVERSITY

- RUS
- 中文
- ES

JOURNAL OF STRUCTURAL CHEMISTRY

Form of presentation

Articles in Russian journals and collections

Year of publication

2024

Язык

английский

Authors, employees of KFU

Gnezdilov Oleg Ivanovich, author

Bibliographic description in the original language

Kuchkaev Aydar M., Kovalentnaya funkcionalizaciya malosloynogo chernogo fosfora kompleksom [NiBr2(phen)], gde phen – 1,10-fenantrolin/ Kuchkaev Ayrat M., Sukhov A.V., Saparina S.V., Gnezdilov O.I., Klimovickiy A.E., Ziganshina S.A., Nizameev I.R., Fayzullin B.A., Sinyashin O.G., Yakhvarov D.G.// ZhSKh. – 2024. - T.65. - №4. -P.124527

Annotation

A 2D material few-layer black phosphorus (FLBP) has promising applications in various fields of chemistry and physics due to its unique electronic and optical properties. Chemical functionalization of the FLBP surface is an effective strategy for improving the oxidative stability of the material, tuning its intrinsic properties or endowing it with new properties. The present work proposes an approach to the immobilization of the [NiBr2(phen)] complex (phen = 1, 10-phenanthroline) on the FLBP surface via covalent functionalization of FLBP with 1,10-phenanthroline and subsequent complexation with NiBr2. The obtained FLBP-based materials functionalized by the [NiBr2(phen)] complex were characterized by a set of physicochemical methods such as transmission electron microscopy, atomic force microscopy, solid-state NMR, energy-dispersive spectroscopy, Raman spectroscopy, and IR spectroscopy.

Keywords

black phosphorus, phosphorene, covalent functionalization, diimine ligands, 1,10-phenanthroline, nickel complexes, diazo compounds

The name of the journal

J STRUCT CHEM+

URL

http:// doi:10.1134/S0022476624040012

Please use this ID to quote from or refer to the card

https://repository.kpfu.ru/eng/?p_id=303881&p_lang=2

Resource files

File name	Size (MB)	Format
F_J_Str_Chem.pdf	2,08	pdf	show / download

Full metadata record

Field DC	Value	Language
dc.contributor.author	Gnezdilov Oleg Ivanovich	ru_RU
dc.date.accessioned	2024-01-01T00:00:00Z	ru_RU
dc.date.available	2024-01-01T00:00:00Z	ru_RU
dc.date.issued	2024	ru_RU
dc.identifier.citation	Кучкаев Айдар М., Ковалентная функционализация малослойного черного фосфора комплексом [NiBr2(phen)], где phen – 1,10-фенантролин/ Кучкаев Айрат М., Сухов А.В., Сапарина С.В., Гнездилов О.И., Климовицкий А.Е., Зиганшина С.А., Низамеев И.Р., Файзуллин Б.А., Синяшин О.Г., Яхваров Д.Г.// ЖСХ. – 2024. - T.65. - №4. -P.124527	ru_RU
dc.identifier.uri	https://repository.kpfu.ru/eng/?p_id=303881&p_lang=2	ru_RU
dc.description.abstract	J STRUCT CHEM+	ru_RU
dc.description.abstract	A 2D material few-layer black phosphorus (FLBP) has promising applications in various fields of chemistry and physics due to its unique electronic and optical properties. Chemical functionalization of the FLBP surface is an effective strategy for improving the oxidative stability of the material, tuning its intrinsic properties or endowing it with new properties. The present work proposes an approach to the immobilization of the [NiBr2(phen)] complex (phen = 1, 10-phenanthroline) on the FLBP surface via covalent functionalization of FLBP with 1,10-phenanthroline and subsequent complexation with NiBr2. The obtained FLBP-based materials functionalized by the [NiBr2(phen)] complex were characterized by a set of physicochemical methods such as transmission electron microscopy, atomic force microscopy, solid-state NMR, energy-dispersive spectroscopy, Raman spectroscopy, and IR spectroscopy.	ru_RU
dc.language.iso	ru	ru_RU
dc.subject	black phosphorus	ru_RU
dc.subject	phosphorene	ru_RU
dc.subject	covalent functionalization	ru_RU
dc.subject	diimine ligands	ru_RU
dc.subject	1	ru_RU
dc.subject	10-phenanthroline	ru_RU
dc.subject	nickel complexes	ru_RU
dc.subject	diazo compounds	ru_RU
dc.title	Journal of Structural Chemistry	ru_RU
dc.type	Articles in Russian journals and collections	ru_RU